Polymer-dispersed liquid-crystal materials fabricated with frontal polymerization
We report on the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A compa...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2003-01, Vol.41 (1), p.204-212 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 41 |
| creator | Gill, N. Pojman, J. A. Willis, J. Whitehead Jr, J. B. |
| description | We report on the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation. Characterization includes differential scanning calorimetry to probe the glass and nematic‐to‐isotropic transitions and scanning electron microscopy to evaluate the phase‐separated morphology. In addition, the frontal temperatures and velocities are reported for PDLCs fabricated with frontal polymerization. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 204–212, 2003
This report investigates the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation. |
| doi_str_mv | 10.1002/pola.10566 |
| format | Article |
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This report investigates the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation.</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.10566</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>New York: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; dispersions ; Exact sciences and technology ; frontal polymerization ; morphology ; Organic polymers ; phase separation ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; thermal properties</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2003-01, Vol.41 (1), p.204-212</ispartof><rights>Copyright © 2002 Wiley Periodicals, Inc.</rights><rights>2003 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3396-e888db669b5eccc99fd9a1cb571b8b5ad690032b66f8a75ccbb185543bfb28f23</citedby><cites>FETCH-LOGICAL-c3396-e888db669b5eccc99fd9a1cb571b8b5ad690032b66f8a75ccbb185543bfb28f23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.10566$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.10566$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14409459$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Gill, N.</creatorcontrib><creatorcontrib>Pojman, J. A.</creatorcontrib><creatorcontrib>Willis, J.</creatorcontrib><creatorcontrib>Whitehead Jr, J. B.</creatorcontrib><title>Polymer-dispersed liquid-crystal materials fabricated with frontal polymerization</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>We report on the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation. Characterization includes differential scanning calorimetry to probe the glass and nematic‐to‐isotropic transitions and scanning electron microscopy to evaluate the phase‐separated morphology. In addition, the frontal temperatures and velocities are reported for PDLCs fabricated with frontal polymerization. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 204–212, 2003
This report investigates the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation.</description><subject>Applied sciences</subject><subject>dispersions</subject><subject>Exact sciences and technology</subject><subject>frontal polymerization</subject><subject>morphology</subject><subject>Organic polymers</subject><subject>phase separation</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>thermal properties</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNp9kL1OwzAURi0EEqWw8ARZWJAMdhI79lgVaJEiWiSgbJbt2MKQNsEOKuHpSQg_G9O9V_d8Z_gAOMboDCMUn9dVKbuNULoDRhhxDhHBbBeMEGMZpHH6uA8OQnhGqPsRNgK3y6ps18bDwoXa-GCKqHSvb66A2rehkWW0lo3xTpYhslJ5p7uziLaueYqsrzY9UQ8K9yEbV20OwZ7taHP0Pcfg_urybjqH-WJ2PZ3kUCcJp9AwxgpFKVfEaK05twWXWCuSYcUUkQXlCCVxR1gmM6K1UpgRkibKqpjZOBmD08GrfRWCN1bU3q2lbwVGoi9D9GWIrzI6-GSAaxm0LK2XG-3CXyJNEU8J7zg8cFtXmvYfo1gu8smPGw4ZFxrz_puR_kXQLMmIWN3MxAPH2UUer8Q8-QT30IDK</recordid><startdate>20030101</startdate><enddate>20030101</enddate><creator>Gill, N.</creator><creator>Pojman, J. A.</creator><creator>Willis, J.</creator><creator>Whitehead Jr, J. B.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20030101</creationdate><title>Polymer-dispersed liquid-crystal materials fabricated with frontal polymerization</title><author>Gill, N. ; Pojman, J. A. ; Willis, J. ; Whitehead Jr, J. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3396-e888db669b5eccc99fd9a1cb571b8b5ad690032b66f8a75ccbb185543bfb28f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>dispersions</topic><topic>Exact sciences and technology</topic><topic>frontal polymerization</topic><topic>morphology</topic><topic>Organic polymers</topic><topic>phase separation</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>thermal properties</topic><toplevel>online_resources</toplevel><creatorcontrib>Gill, N.</creatorcontrib><creatorcontrib>Pojman, J. A.</creatorcontrib><creatorcontrib>Willis, J.</creatorcontrib><creatorcontrib>Whitehead Jr, J. B.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gill, N.</au><au>Pojman, J. A.</au><au>Willis, J.</au><au>Whitehead Jr, J. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer-dispersed liquid-crystal materials fabricated with frontal polymerization</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2003-01-01</date><risdate>2003</risdate><volume>41</volume><issue>1</issue><spage>204</spage><epage>212</epage><pages>204-212</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>We report on the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation. Characterization includes differential scanning calorimetry to probe the glass and nematic‐to‐isotropic transitions and scanning electron microscopy to evaluate the phase‐separated morphology. In addition, the frontal temperatures and velocities are reported for PDLCs fabricated with frontal polymerization. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 204–212, 2003
This report investigates the morphological and thermal properties of polymer‐dispersed liquid crystals (PDLCs) fabricated with frontal‐polymerization‐induced phase separation (FPIPS). Frontal polymerization is characterized by a rapid‐conversion, high‐temperature, and large‐thermal‐gradient environment. A comparison is made between the morphological and thermal properties of PDLCs fabricated with FPIPS and traditional thermal‐polymerization‐induced phase separation.</abstract><cop>New York</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.10566</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied sciences dispersions Exact sciences and technology frontal polymerization morphology Organic polymers phase separation Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts thermal properties |
| title | Polymer-dispersed liquid-crystal materials fabricated with frontal polymerization |
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