Wetting properties of polyacetylene films
The wetting characteristics of free‐standing polyacetylene films were determined by using a standard series of wetting liquids. As‐prepared films of cis ‐polyacetylene were found to contain a significant polar contribution to the surface free energy, which became nearly entirely dispersive upon ther...
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| Veröffentlicht in: | Journal of polymer science. Polymer physics edition 1985-08, Vol.23 (8), p.1555-1562 |
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| container_end_page | 1562 |
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| container_issue | 8 |
| container_start_page | 1555 |
| container_title | Journal of polymer science. Polymer physics edition |
| container_volume | 23 |
| creator | Schonhorn, H. Baker, G. L. Bates, F. S. |
| description | The wetting characteristics of free‐standing polyacetylene films were determined by using a standard series of wetting liquids. As‐prepared films of
cis
‐polyacetylene were found to contain a significant polar contribution to the surface free energy, which became nearly entirely dispersive upon thermal isomerization to the
trans
form. Both isomeric forms are characterized by a critical surface tension of wetting γ
c
≈ 51 mN/m, which is considerably higher than that normally obtained from organic polymers. These results have been interpreted with respect to surface oxidation and tested by examining an oxidized film. |
| doi_str_mv | 10.1002/pol.1985.180230808 |
| format | Article |
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cis
‐polyacetylene were found to contain a significant polar contribution to the surface free energy, which became nearly entirely dispersive upon thermal isomerization to the
trans
form. Both isomeric forms are characterized by a critical surface tension of wetting γ
c
≈ 51 mN/m, which is considerably higher than that normally obtained from organic polymers. These results have been interpreted with respect to surface oxidation and tested by examining an oxidized film.</description><identifier>ISSN: 0098-1273</identifier><identifier>EISSN: 1542-9385</identifier><identifier>DOI: 10.1002/pol.1985.180230808</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Surface properties</subject><ispartof>Journal of polymer science. Polymer physics edition, 1985-08, Vol.23 (8), p.1555-1562</ispartof><rights>1985 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c312t-e71f0fd5ccdb6e5812482bf12fb416271d77aba9431485619fc05ab1416e8caa3</citedby><cites>FETCH-LOGICAL-c312t-e71f0fd5ccdb6e5812482bf12fb416271d77aba9431485619fc05ab1416e8caa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9290654$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Schonhorn, H.</creatorcontrib><creatorcontrib>Baker, G. L.</creatorcontrib><creatorcontrib>Bates, F. S.</creatorcontrib><title>Wetting properties of polyacetylene films</title><title>Journal of polymer science. Polymer physics edition</title><addtitle>J. Polym. Sci. Polym. Phys. Ed</addtitle><description>The wetting characteristics of free‐standing polyacetylene films were determined by using a standard series of wetting liquids. As‐prepared films of
cis
‐polyacetylene were found to contain a significant polar contribution to the surface free energy, which became nearly entirely dispersive upon thermal isomerization to the
trans
form. Both isomeric forms are characterized by a critical surface tension of wetting γ
c
≈ 51 mN/m, which is considerably higher than that normally obtained from organic polymers. These results have been interpreted with respect to surface oxidation and tested by examining an oxidized film.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Surface properties</subject><issn>0098-1273</issn><issn>1542-9385</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNo9j7FOwzAURS0EEqHwA0wZWBhS3rPj2B5RgRapwFBQJRbLcW0USJPIzkD-nlRBnd5w77l6h5BrhDkC0LuureeoJJ-jBMpAgjwhCfKcZopJfkoSACUzpIKdk4sYvwEYgigScrt1fV81X2kX2s6FvnIxbX067g3Gun6oXeNSX9X7eEnOvKmju_q_M_Lx9Pi-WGXrt-Xz4n6dWYa0z5xAD37Hrd2VheMSaS5p6ZH6MseCCtwJYUqjcoa55AUqb4GbEsfQSWsMmxE67drQxhic112o9iYMGkEfZPX4nD7I6qPsCN1MUGeiNbUPprFVPJKKKih4PtayqVbF3v0eYxN-dCGY4Hr7utTLzSd72Kxe9Jr9ARhNZAQ</recordid><startdate>198508</startdate><enddate>198508</enddate><creator>Schonhorn, H.</creator><creator>Baker, G. L.</creator><creator>Bates, F. S.</creator><general>John Wiley & Sons, Inc</general><general>Interscience</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198508</creationdate><title>Wetting properties of polyacetylene films</title><author>Schonhorn, H. ; Baker, G. L. ; Bates, F. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-e71f0fd5ccdb6e5812482bf12fb416271d77aba9431485619fc05ab1416e8caa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Surface properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schonhorn, H.</creatorcontrib><creatorcontrib>Baker, G. L.</creatorcontrib><creatorcontrib>Bates, F. S.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Polymer physics edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schonhorn, H.</au><au>Baker, G. L.</au><au>Bates, F. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Wetting properties of polyacetylene films</atitle><jtitle>Journal of polymer science. Polymer physics edition</jtitle><addtitle>J. Polym. Sci. Polym. Phys. Ed</addtitle><date>1985-08</date><risdate>1985</risdate><volume>23</volume><issue>8</issue><spage>1555</spage><epage>1562</epage><pages>1555-1562</pages><issn>0098-1273</issn><eissn>1542-9385</eissn><abstract>The wetting characteristics of free‐standing polyacetylene films were determined by using a standard series of wetting liquids. As‐prepared films of
cis
‐polyacetylene were found to contain a significant polar contribution to the surface free energy, which became nearly entirely dispersive upon thermal isomerization to the
trans
form. Both isomeric forms are characterized by a critical surface tension of wetting γ
c
≈ 51 mN/m, which is considerably higher than that normally obtained from organic polymers. These results have been interpreted with respect to surface oxidation and tested by examining an oxidized film.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pol.1985.180230808</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0098-1273 |
| ispartof | Journal of polymer science. Polymer physics edition, 1985-08, Vol.23 (8), p.1555-1562 |
| issn | 0098-1273 1542-9385 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pol_1985_180230808 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Surface properties |
| title | Wetting properties of polyacetylene films |
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