Fourier transform infrared study of the gel form of isotactic polystyrene
Infrared spectra of isotactic polystyrene gel films are observed to be significantly different from those of amorphous and crystalline polymer, indicating that the gel form is in a different conformation than the usual 3 1 helical crystal structure. Computer‐assisted subtraction indicates that appro...
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| Veröffentlicht in: | Journal of polymer science. Polymer physics edition 1980-04, Vol.18 (4), p.723-729 |
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| Sprache: | eng |
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| container_end_page | 729 |
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| container_issue | 4 |
| container_start_page | 723 |
| container_title | Journal of polymer science. Polymer physics edition |
| container_volume | 18 |
| creator | Painter, Paul C. Kessler, Richard E. Snyder, Randy W. |
| description | Infrared spectra of isotactic polystyrene gel films are observed to be significantly different from those of amorphous and crystalline polymer, indicating that the gel form is in a different conformation than the usual 3
1
helical crystal structure. Computer‐assisted subtraction indicates that approximately 35% of the chains participate in the gel component, effectively ruling out structural defects as the origin of the ordered gel component. |
| doi_str_mv | 10.1002/pol.1980.180180405 |
| format | Article |
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1
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| identifier | ISSN: 0098-1273 |
| ispartof | Journal of polymer science. Polymer physics edition, 1980-04, Vol.18 (4), p.723-729 |
| issn | 0098-1273 1542-9385 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pol_1980_180180405 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Fourier transform infrared study of the gel form of isotactic polystyrene |
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