Solvating properties of certain polymeric ethers
The formation of two kinds of solvation complex of poly(ethylene oxide), polydimethoxyethylene, and polydioxene with some alkali derivatives of fluorene in dioxane was found, differing in the ionic species of the fluorenyl metal in the complex. Additional evidence was found for the existence of peri...
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| Veröffentlicht in: | Journal of polymer science. Polymer chemistry edition 1980-10, Vol.18 (10), p.3059-3067 |
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| container_end_page | 3067 |
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| container_issue | 10 |
| container_start_page | 3059 |
| container_title | Journal of polymer science. Polymer chemistry edition |
| container_volume | 18 |
| creator | Panayotov, I. M. Dimov, D. K. Tsvetanov, Ch. B. Stepanov, V. V. Skorokhodov, S. S. |
| description | The formation of two kinds of solvation complex of poly(ethylene oxide), polydimethoxyethylene, and polydioxene with some alkali derivatives of fluorene in dioxane was found, differing in the ionic species of the fluorenyl metal in the complex. Additional evidence was found for the existence of peripherally solvated ion pairs of fluorenyllithium, ‐sodium, and ‐potassium. It was shown that polydimethoxyethylene and polydioxane interact with different cations in a different manner. The complexing ability of poly(ethylene oxide) and polydioxane with respect to fluorenyllithium, ‐sodium, and ‐potassium, and of polydimethoxyethylene for fluorenyllithium, was proved to be stronger than that of their monomer analogs—dimethoxyethane and dioxane. This was explained by the effect of the polymer chain. |
| doi_str_mv | 10.1002/pol.1980.170181015 |
| format | Article |
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The complexing ability of poly(ethylene oxide) and polydioxane with respect to fluorenyllithium, ‐sodium, and ‐potassium, and of polydimethoxyethylene for fluorenyllithium, was proved to be stronger than that of their monomer analogs—dimethoxyethane and dioxane. This was explained by the effect of the polymer chain.</description><issn>0360-6376</issn><issn>1542-9369</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1980</creationdate><recordtype>article</recordtype><recordid>eNqNj81KxDAUhYMoWEdfwFVfoOO9SfMHbmTwDwZGUNchTRONdKYlKUrf3g4junV1z118h_MRcomwRAB6NfTdErWaPwmoEJAfkQJ5TSvNhD4mBTABlWBSnJKznD8AGIKsCwLPffdpx7h7K4fUDz6N0eeyD6Wbo427cm6etj5FV_rx3ad8Tk6C7bK_-LkL8np3-7J6qNab-8fVzbpyVCteBRlsY1kjmWsUFxQlIqVAg-c1b1slQGKLoKjSARyiAADtLLfSeYuyYQtCD70u9TknH8yQ4tamySCYvbOZl5m9s_l1nqHrA_QVOz_9gzBPm_Uf_g1wYluO</recordid><startdate>198010</startdate><enddate>198010</enddate><creator>Panayotov, I. M.</creator><creator>Dimov, D. K.</creator><creator>Tsvetanov, Ch. 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This was explained by the effect of the polymer chain.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pol.1980.170181015</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 0360-6376 |
| ispartof | Journal of polymer science. Polymer chemistry edition, 1980-10, Vol.18 (10), p.3059-3067 |
| issn | 0360-6376 1542-9369 |
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| source | Access via Wiley Online Library |
| title | Solvating properties of certain polymeric ethers |
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