ESR study of pressure and temperature dependence of free‐radical decay in poly(vinyl chloride)

Gamma‐irradiated poly(vinyl chloride) was annealed at various temperatures (80 to 140°C) and pressures (0.1 to 800 MN m −2 ). Rate constants and activation volumes of free‐radical decay were determined from the changes of the electron spin resonance (ESR) spectra before and after annealing. The pres...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	J. Polym. Sci., Polym. Chem. Ed.; (United States) Polym. Chem. Ed.; (United States), 1977-11, Vol.15 (11), p.1983-1988
Hauptverfasser:	Szoecs, F., Klimova, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	400600 - Radiation Chemistry CHEMICAL RADIATION EFFECTS CHEMICAL REACTIONS CHEMISTRY CHLORINATED ALIPHATIC HYDROCARBONS DECOMPOSITION ELECTRON SPIN RESONANCE HALOGENATED ALIPHATIC HYDROCARBONS MAGNETIC RESONANCE ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORGANIC POLYMERS POLYMERS POLYVINYLS PRESSURE DEPENDENCE PVC RADIATION CHEMISTRY RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADICALS RADIOLYSIS RESONANCE TEMPERATURE DEPENDENCE
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!