Heat‐resistant polymers containing bipyridyl units. I. Polyimides
Polyimides containing bipyridyl units were synthesized. The bipyridyl units were successfully incorporated by polymerization of various bipyridyl diamines with aromatic tetracarboxylic acid dianhydrides. The resulting polyamic acids had inherent viscosities in the range 0.07 to 2.26, and they were c...
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| Veröffentlicht in: | Journal of polymer science. Polymer chemistry edition 1973-12, Vol.11 (12), p.3125-3150 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Polyimides containing bipyridyl units were synthesized. The bipyridyl units were successfully incorporated by polymerization of various bipyridyl diamines with aromatic tetracarboxylic acid dianhydrides. The resulting polyamic acids had inherent viscosities in the range 0.07 to 2.26, and they were converted to the polyimides by thermal cyclization. The polyimides containing the bipyridyl units exhibited varying degrees of solubility in dimethylacetamide and m‐cresol and were found to be very soluble in dichloroacetic acid. |
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| ISSN: | 0360-6376 1542-9369 |
| DOI: | 10.1002/pol.1973.170111208 |