Kinetics of alternating copolymerization
The rates of copolymerization of three monomer pairs which form only alternating copolymers have been studied. The monomer pairs were vinyl isobutyl ether–diethyl fumarate, vinyl isobutyl ether–maleic anhydride, and 1‐octene–maleic anhydride. It was shown that the maximum copolymerization rate occur...
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| Veröffentlicht in: | Journal of polymer science. Part A. General papers 1965-02, Vol.3 (2), p.703-710 |
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| Format: | Artikel |
| Sprache: | eng |
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| container_end_page | 710 |
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| container_issue | 2 |
| container_start_page | 703 |
| container_title | Journal of polymer science. Part A. General papers |
| container_volume | 3 |
| creator | Baldwin, M. G. |
| description | The rates of copolymerization of three monomer pairs which form only alternating copolymers have been studied. The monomer pairs were vinyl isobutyl ether–diethyl fumarate, vinyl isobutyl ether–maleic anhydride, and 1‐octene–maleic anhydride. It was shown that the maximum copolymerization rate occurs at [M
1
]/[M
2
] ratios which differ significantly from unity, for a fixed total monomer concentration ([M
1
] + [M
2
]). An equation for the rate of copolymerization for alternating systems is given and the results are discussed in terms of the equation. |
| doi_str_mv | 10.1002/pol.1965.100030226 |
| format | Article |
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1
]/[M
2
] ratios which differ significantly from unity, for a fixed total monomer concentration ([M
1
] + [M
2
]). An equation for the rate of copolymerization for alternating systems is given and the results are discussed in terms of the equation.</description><identifier>ISSN: 0449-2951</identifier><identifier>EISSN: 1542-6246</identifier><identifier>DOI: 10.1002/pol.1965.100030226</identifier><language>eng</language><ispartof>Journal of polymer science. Part A. General papers, 1965-02, Vol.3 (2), p.703-710</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c243t-3a880db0a8df5c92a16626df308a1b87925947a9fe3363c8cbc150599291fef23</citedby><cites>FETCH-LOGICAL-c243t-3a880db0a8df5c92a16626df308a1b87925947a9fe3363c8cbc150599291fef23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Baldwin, M. G.</creatorcontrib><title>Kinetics of alternating copolymerization</title><title>Journal of polymer science. Part A. General papers</title><description>The rates of copolymerization of three monomer pairs which form only alternating copolymers have been studied. The monomer pairs were vinyl isobutyl ether–diethyl fumarate, vinyl isobutyl ether–maleic anhydride, and 1‐octene–maleic anhydride. It was shown that the maximum copolymerization rate occurs at [M
1
]/[M
2
] ratios which differ significantly from unity, for a fixed total monomer concentration ([M
1
] + [M
2
]). An equation for the rate of copolymerization for alternating systems is given and the results are discussed in terms of the equation.</description><issn>0449-2951</issn><issn>1542-6246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1965</creationdate><recordtype>article</recordtype><recordid>eNo9j09LxDAUxIMoWFe_gKcevXR9efnTvKMs6ooLXnbPIU0TqXTbJell_fS2KJ6GGYZhfozdc1hzAHw8jf2ak1aLAwGI-oIVXEmsNEp9yQqQkiokxa_ZTc5fcwlrpII9vHdDmDqfyzGWrp9CGtzUDZ-lH-fN8zGk7nsOxuGWXUXX53D3pyt2eHneb7bV7uP1bfO0qzxKMVXCGQNtA860UXlCx7VG3UYBxvHG1ISKZO0oBiG08MY3nitQREg8hohixfB316cx5xSiPaXu6NLZcrALq51_2YXV_rOKH0fjR20</recordid><startdate>196502</startdate><enddate>196502</enddate><creator>Baldwin, M. G.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>196502</creationdate><title>Kinetics of alternating copolymerization</title><author>Baldwin, M. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c243t-3a880db0a8df5c92a16626df308a1b87925947a9fe3363c8cbc150599291fef23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1965</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Baldwin, M. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of polymer science. Part A. General papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baldwin, M. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of alternating copolymerization</atitle><jtitle>Journal of polymer science. Part A. General papers</jtitle><date>1965-02</date><risdate>1965</risdate><volume>3</volume><issue>2</issue><spage>703</spage><epage>710</epage><pages>703-710</pages><issn>0449-2951</issn><eissn>1542-6246</eissn><abstract>The rates of copolymerization of three monomer pairs which form only alternating copolymers have been studied. The monomer pairs were vinyl isobutyl ether–diethyl fumarate, vinyl isobutyl ether–maleic anhydride, and 1‐octene–maleic anhydride. It was shown that the maximum copolymerization rate occurs at [M
1
]/[M
2
] ratios which differ significantly from unity, for a fixed total monomer concentration ([M
1
] + [M
2
]). An equation for the rate of copolymerization for alternating systems is given and the results are discussed in terms of the equation.</abstract><doi>10.1002/pol.1965.100030226</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0449-2951 |
| ispartof | Journal of polymer science. Part A. General papers, 1965-02, Vol.3 (2), p.703-710 |
| issn | 0449-2951 1542-6246 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pol_1965_100030226 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Kinetics of alternating copolymerization |
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