The accelerating effect of methanol on the gamma radiation-induced graft copolymerization of styrene to polyethylene

Dilution of styrene in its gamma radiation-induced graft copolymerization to polyethylene with methanol was found to increase the rate of grafting. This effect is at a maximum at about 50% by volumel MeOH concentration and is ascribed to a Trommsdorff-type acceleration. This acceleration can explain...

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Veröffentlicht in:	J. Polymer Sci 1960-02, Vol.42 (140), p.575-578
Hauptverfasser:	Odian, George G., Rossi, Albert, Trachtenberg, Edward N.
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL REACTIONS CHEMISTRY GAMMA RADIATION METHANOL POLYETHYLENES POLYMERIZATION QUANTITY RATIO RADIATION EFFECTS REACTION KINETICS STYRENE
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