Heats of formation of enols. The double-bond stabilizing effect of the hydroxyl group

Aqueous solution free energies of ketonization have been combined with enthalpies of reduction of the keto forms and other thermochemical data to yield estimates of the heats of formation of the corresponding enols. A double‐bond stabilization term, DOH = 5.4 ± 0.5 kcal mol−1 (1 kcal = 4.184 kJ), is...

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Veröffentlicht in:	Journal of physical organic chemistry 1992-09, Vol.5 (9), p.575-580
Hauptverfasser:	Keeffe, J. R., Kresge, A. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical thermodynamics Chemistry Elements, mineral and organic compounds Exact sciences and technology General and physical chemistry Thermodynamic properties
Online-Zugang:	Volltext
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