The Grunwald-Winstein relationship in the solvolysis of crowded tertiary alkyl chlorides. Hindered hydration and hydrophobic effect

Various highly crowded tertiary alkyl chlorides having a neopentyl or a (1‐adamantyl)methyl substituent on the reaction center were subjected to solvolysis rate studies, and the Grunwald–Winstein (GW) type relationship with respect to the YCl scale was examined. Analyses of the plots showed that the...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of physical organic chemistry 2001-04, Vol.14 (4), p.229-238
Hauptverfasser:	Takeuchi, Ken'ichi, Takasuka, Masaaki, Shiba, Eiji, Tokunaga, Hironobu, Endo, Tadasuke, Ushino, Takuhiro, Tokunaga, Kazuhiko, Okazaki, Takao, Kinoshita, Tomomi, Ohga, Yasushi
Format:	Artikel
Sprache:	eng
Schlagworte:	Grunwald-Winstein relationship hydrophobic effect solvation solvent effect solvolysis rate steric congestion tertiary alkyl chloride
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!