Synthesis and characterization of poly(methyl methacrylate) star polymers
Star‐branched poly(methyl methacrylate)s (PMMA) were synthesized by linking ‘living’ arms (produced by anionic polymerzation) with ethylene glycol dimethacrylate. Stars having arm molecular weights of 10000 and 40000 and between 4.9 and 18.7 branches were produced. The polymers were characterized us...
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| Veröffentlicht in: | Polymer international 1994-02, Vol.33 (2), p.171-179 |
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| container_title | Polymer international |
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| creator | Efstratiadis, Vasilis Tselikas, Giannis Hadjichristidis, Nikos Li, Jianbo Yunan, Wan Mays, Jimmy W. |
| description | Star‐branched poly(methyl methacrylate)s (PMMA) were synthesized by linking ‘living’ arms (produced by anionic polymerzation) with ethylene glycol dimethacrylate. Stars having arm molecular weights of 10000 and 40000 and between 4.9 and 18.7 branches were produced. The polymers were characterized using light scattering, size exclusion chromatography, and viscometry. It was found that well‐defined PMMA stars were obtained only at the higher (40000) arm molecular weight. The stars prepared using the lower molecular weight (c. 10000) arms contained very high molecular weight gel components. |
| doi_str_mv | 10.1002/pi.1994.210330208 |
| format | Article |
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Stars having arm molecular weights of 10000 and 40000 and between 4.9 and 18.7 branches were produced. The polymers were characterized using light scattering, size exclusion chromatography, and viscometry. It was found that well‐defined PMMA stars were obtained only at the higher (40000) arm molecular weight. The stars prepared using the lower molecular weight (c. 10000) arms contained very high molecular weight gel components.</description><identifier>ISSN: 0959-8103</identifier><identifier>EISSN: 1097-0126</identifier><identifier>DOI: 10.1002/pi.1994.210330208</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Applied sciences ; Exact sciences and technology ; gelation ; intrinsic viscosity ; Organic polymers ; Physicochemistry of polymers ; poly(methyl methacrylate) ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; star polymer</subject><ispartof>Polymer international, 1994-02, Vol.33 (2), p.171-179</ispartof><rights>1994 Society of Chemical Industry</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4278-db318a7a2c3c0f52aa67d4da4112c91601e224d474413bcedb06fb94b183c1003</citedby><cites>FETCH-LOGICAL-c4278-db318a7a2c3c0f52aa67d4da4112c91601e224d474413bcedb06fb94b183c1003</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpi.1994.210330208$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpi.1994.210330208$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3934500$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Efstratiadis, Vasilis</creatorcontrib><creatorcontrib>Tselikas, Giannis</creatorcontrib><creatorcontrib>Hadjichristidis, Nikos</creatorcontrib><creatorcontrib>Li, Jianbo</creatorcontrib><creatorcontrib>Yunan, Wan</creatorcontrib><creatorcontrib>Mays, Jimmy W.</creatorcontrib><title>Synthesis and characterization of poly(methyl methacrylate) star polymers</title><title>Polymer international</title><addtitle>Polym. 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The stars prepared using the lower molecular weight (c. 10000) arms contained very high molecular weight gel components.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>gelation</subject><subject>intrinsic viscosity</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(methyl methacrylate)</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>star polymer</subject><issn>0959-8103</issn><issn>1097-0126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLw0AUhQdRsFZ_gLssXOgi9c4jj3EnRWtL8UEVwc1wM5nQ0TQJMwGNv962keLO1Vmc-53DPYScUhhRAHbZ2BGVUowYBc6BQbpHBhRkEgJl8T4ZgIxkmK7NQ3Lk_TsApFLKAZkuuqpdGm99gFUe6CU61K1x9htbW1dBXQRNXXbnK9MuuzLYCGrXldiai8C36Lb2yjh_TA4KLL05-dUhebm9eR7fhfOHyXR8PQ-1YEka5hmnKSbINNdQRAwxTnKRo6CUaUljoIYxkYtECMozbfIM4iKTIqMp1-tX-ZDQPle72ntnCtU4u0LXKQpqs4VqrNpsoXZbrJmznmnQaywLh5W2fgdyyUW0jb7qzz5tabr_c9Xj9G9H2MPWt-ZrB6P7UHHCk0i93k_U01jOZskiVW_8B6YIf2U</recordid><startdate>199402</startdate><enddate>199402</enddate><creator>Efstratiadis, Vasilis</creator><creator>Tselikas, Giannis</creator><creator>Hadjichristidis, Nikos</creator><creator>Li, Jianbo</creator><creator>Yunan, Wan</creator><creator>Mays, Jimmy W.</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199402</creationdate><title>Synthesis and characterization of poly(methyl methacrylate) star polymers</title><author>Efstratiadis, Vasilis ; Tselikas, Giannis ; Hadjichristidis, Nikos ; Li, Jianbo ; Yunan, Wan ; Mays, Jimmy W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4278-db318a7a2c3c0f52aa67d4da4112c91601e224d474413bcedb06fb94b183c1003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>gelation</topic><topic>intrinsic viscosity</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(methyl methacrylate)</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>star polymer</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Efstratiadis, Vasilis</creatorcontrib><creatorcontrib>Tselikas, Giannis</creatorcontrib><creatorcontrib>Hadjichristidis, Nikos</creatorcontrib><creatorcontrib>Li, Jianbo</creatorcontrib><creatorcontrib>Yunan, Wan</creatorcontrib><creatorcontrib>Mays, Jimmy W.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Polymer international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Efstratiadis, Vasilis</au><au>Tselikas, Giannis</au><au>Hadjichristidis, Nikos</au><au>Li, Jianbo</au><au>Yunan, Wan</au><au>Mays, Jimmy W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of poly(methyl methacrylate) star polymers</atitle><jtitle>Polymer international</jtitle><addtitle>Polym. Int</addtitle><date>1994-02</date><risdate>1994</risdate><volume>33</volume><issue>2</issue><spage>171</spage><epage>179</epage><pages>171-179</pages><issn>0959-8103</issn><eissn>1097-0126</eissn><abstract>Star‐branched poly(methyl methacrylate)s (PMMA) were synthesized by linking ‘living’ arms (produced by anionic polymerzation) with ethylene glycol dimethacrylate. Stars having arm molecular weights of 10000 and 40000 and between 4.9 and 18.7 branches were produced. The polymers were characterized using light scattering, size exclusion chromatography, and viscometry. It was found that well‐defined PMMA stars were obtained only at the higher (40000) arm molecular weight. The stars prepared using the lower molecular weight (c. 10000) arms contained very high molecular weight gel components.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pi.1994.210330208</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0959-8103 |
| ispartof | Polymer international, 1994-02, Vol.33 (2), p.171-179 |
| issn | 0959-8103 1097-0126 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pi_1994_210330208 |
| source | Wiley Journals |
| subjects | Applied sciences Exact sciences and technology gelation intrinsic viscosity Organic polymers Physicochemistry of polymers poly(methyl methacrylate) Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts star polymer |
| title | Synthesis and characterization of poly(methyl methacrylate) star polymers |
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