1 H‐NMR Fingerprinting of Vaccinium vitis‐idaea Flavonol Glycosides
The present study fully interpreted the complex 1 H NMR fingerprints of quercetin (Q) glycosides (QGs) obtained from the berries of V. vitis‐idaea and provided complete and unambiguous signal assignments. QGs were purified by long‐bed gel permeation chromatography and identified by comparison to com...
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| Veröffentlicht in: | Phytochemical analysis 2013-09, Vol.24 (5), p.476-483 |
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| container_title | Phytochemical analysis |
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| creator | Riihinen, Kaisu R. Mihaleva, Velitchka V. Gödecke, Tanja Soininen, Pasi Laatikainen, Reino Vervoort, Jacques M. Lankin, David C. Pauli, Guido F. |
| description | The present study fully interpreted the complex
1
H NMR fingerprints of quercetin (Q) glycosides (QGs) obtained from the berries of
V. vitis‐idaea
and provided complete and unambiguous signal assignments. QGs were purified by long‐bed gel permeation chromatography and identified by comparison to commercially available compounds using LC‐MS‐IT‐TOF and 1D/2D NMR. Q‐3‐
O
‐β‐glucopyranoside and Q‐3‐
O
‐β‐glucuronopyranoside were revealed in the berries of
V. vitis‐idaea
for the first time, and the structures of Q‐3‐
O
‐[4″‐(3‐hydroxy‐3‐methylglutaroyl)]‐α‐rhamnopyranoside, Q‐3‐
O
‐α‐rhamnopyranoside, Q‐3‐
O
‐β‐galactopyranoside, Q‐3‐
O
‐a‐arabinofuranoside, Q‐3‐
O
‐b‐xylopyranoside, and Q‐3‐
O
‐a‐arabinopyranoside were unambiguously confirmed. |
| doi_str_mv | 10.1002/pca.2444 |
| format | Article |
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1
H NMR fingerprints of quercetin (Q) glycosides (QGs) obtained from the berries of
V. vitis‐idaea
and provided complete and unambiguous signal assignments. QGs were purified by long‐bed gel permeation chromatography and identified by comparison to commercially available compounds using LC‐MS‐IT‐TOF and 1D/2D NMR. Q‐3‐
O
‐β‐glucopyranoside and Q‐3‐
O
‐β‐glucuronopyranoside were revealed in the berries of
V. vitis‐idaea
for the first time, and the structures of Q‐3‐
O
‐[4″‐(3‐hydroxy‐3‐methylglutaroyl)]‐α‐rhamnopyranoside, Q‐3‐
O
‐α‐rhamnopyranoside, Q‐3‐
O
‐β‐galactopyranoside, Q‐3‐
O
‐a‐arabinofuranoside, Q‐3‐
O
‐b‐xylopyranoside, and Q‐3‐
O
‐a‐arabinopyranoside were unambiguously confirmed.</description><identifier>ISSN: 0958-0344</identifier><identifier>EISSN: 1099-1565</identifier><identifier>DOI: 10.1002/pca.2444</identifier><language>eng</language><ispartof>Phytochemical analysis, 2013-09, Vol.24 (5), p.476-483</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c724-ad3d71627ae8f84143b3a99e86485e9d5973448ee85b8e4adc9b0cd01e324e543</citedby><cites>FETCH-LOGICAL-c724-ad3d71627ae8f84143b3a99e86485e9d5973448ee85b8e4adc9b0cd01e324e543</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Riihinen, Kaisu R.</creatorcontrib><creatorcontrib>Mihaleva, Velitchka V.</creatorcontrib><creatorcontrib>Gödecke, Tanja</creatorcontrib><creatorcontrib>Soininen, Pasi</creatorcontrib><creatorcontrib>Laatikainen, Reino</creatorcontrib><creatorcontrib>Vervoort, Jacques M.</creatorcontrib><creatorcontrib>Lankin, David C.</creatorcontrib><creatorcontrib>Pauli, Guido F.</creatorcontrib><title>1 H‐NMR Fingerprinting of Vaccinium vitis‐idaea Flavonol Glycosides</title><title>Phytochemical analysis</title><description>The present study fully interpreted the complex
1
H NMR fingerprints of quercetin (Q) glycosides (QGs) obtained from the berries of
V. vitis‐idaea
and provided complete and unambiguous signal assignments. QGs were purified by long‐bed gel permeation chromatography and identified by comparison to commercially available compounds using LC‐MS‐IT‐TOF and 1D/2D NMR. Q‐3‐
O
‐β‐glucopyranoside and Q‐3‐
O
‐β‐glucuronopyranoside were revealed in the berries of
V. vitis‐idaea
for the first time, and the structures of Q‐3‐
O
‐[4″‐(3‐hydroxy‐3‐methylglutaroyl)]‐α‐rhamnopyranoside, Q‐3‐
O
‐α‐rhamnopyranoside, Q‐3‐
O
‐β‐galactopyranoside, Q‐3‐
O
‐a‐arabinofuranoside, Q‐3‐
O
‐b‐xylopyranoside, and Q‐3‐
O
‐a‐arabinopyranoside were unambiguously confirmed.</description><issn>0958-0344</issn><issn>1099-1565</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNotj9FKwzAYhYMoWKfgI-TSm8yk-dMmlzJsJ0wFGd6WNPkrka4dzRzszkfwGX2SZejVOXAOh_MRciv4XHCe32-dnecAcEYywY1hQhXqnGTcKM24BLgkVzF-cp4yU2SkFnT5-_3z8vxGqzB84LSdwrBLjo4dfbfOhSF8beg-7EJMveAtWlr1dj8OY0_r_uDGGDzGa3LR2T7izb_OyLp6XC-WbPVaPy0eVsyVOTDrpS9FkZcWdadBgGylNQZ1AVqh8cqU6aJG1KrVCNY703LnuUCZAyqQM3L3N-umMcYJuyb93djp0AjenPibxN-c-OURFA5PDA</recordid><startdate>201309</startdate><enddate>201309</enddate><creator>Riihinen, Kaisu R.</creator><creator>Mihaleva, Velitchka V.</creator><creator>Gödecke, Tanja</creator><creator>Soininen, Pasi</creator><creator>Laatikainen, Reino</creator><creator>Vervoort, Jacques M.</creator><creator>Lankin, David C.</creator><creator>Pauli, Guido F.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201309</creationdate><title>1 H‐NMR Fingerprinting of Vaccinium vitis‐idaea Flavonol Glycosides</title><author>Riihinen, Kaisu R. ; Mihaleva, Velitchka V. ; Gödecke, Tanja ; Soininen, Pasi ; Laatikainen, Reino ; Vervoort, Jacques M. ; Lankin, David C. ; Pauli, Guido F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c724-ad3d71627ae8f84143b3a99e86485e9d5973448ee85b8e4adc9b0cd01e324e543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Riihinen, Kaisu R.</creatorcontrib><creatorcontrib>Mihaleva, Velitchka V.</creatorcontrib><creatorcontrib>Gödecke, Tanja</creatorcontrib><creatorcontrib>Soininen, Pasi</creatorcontrib><creatorcontrib>Laatikainen, Reino</creatorcontrib><creatorcontrib>Vervoort, Jacques M.</creatorcontrib><creatorcontrib>Lankin, David C.</creatorcontrib><creatorcontrib>Pauli, Guido F.</creatorcontrib><collection>CrossRef</collection><jtitle>Phytochemical analysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Riihinen, Kaisu R.</au><au>Mihaleva, Velitchka V.</au><au>Gödecke, Tanja</au><au>Soininen, Pasi</au><au>Laatikainen, Reino</au><au>Vervoort, Jacques M.</au><au>Lankin, David C.</au><au>Pauli, Guido F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1 H‐NMR Fingerprinting of Vaccinium vitis‐idaea Flavonol Glycosides</atitle><jtitle>Phytochemical analysis</jtitle><date>2013-09</date><risdate>2013</risdate><volume>24</volume><issue>5</issue><spage>476</spage><epage>483</epage><pages>476-483</pages><issn>0958-0344</issn><eissn>1099-1565</eissn><abstract>The present study fully interpreted the complex
1
H NMR fingerprints of quercetin (Q) glycosides (QGs) obtained from the berries of
V. vitis‐idaea
and provided complete and unambiguous signal assignments. QGs were purified by long‐bed gel permeation chromatography and identified by comparison to commercially available compounds using LC‐MS‐IT‐TOF and 1D/2D NMR. Q‐3‐
O
‐β‐glucopyranoside and Q‐3‐
O
‐β‐glucuronopyranoside were revealed in the berries of
V. vitis‐idaea
for the first time, and the structures of Q‐3‐
O
‐[4″‐(3‐hydroxy‐3‐methylglutaroyl)]‐α‐rhamnopyranoside, Q‐3‐
O
‐α‐rhamnopyranoside, Q‐3‐
O
‐β‐galactopyranoside, Q‐3‐
O
‐a‐arabinofuranoside, Q‐3‐
O
‐b‐xylopyranoside, and Q‐3‐
O
‐a‐arabinopyranoside were unambiguously confirmed.</abstract><doi>10.1002/pca.2444</doi><tpages>8</tpages></addata></record> |
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| ispartof | Phytochemical analysis, 2013-09, Vol.24 (5), p.476-483 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | 1 H‐NMR Fingerprinting of Vaccinium vitis‐idaea Flavonol Glycosides |
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