Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites
Preparation and analysis of morphology, mechanical, and electrical properties of nanocomposites based on ethylene vinyl acetate (EVA) copolymer and commercial multiwalled carbon nanotubes (CNTs) was achieved. The used techniques for obtaining nanocomposites were the conventional melt‐mixing and the...
Gespeichert in:
| Veröffentlicht in: | Polymers for advanced technologies 2012-11, Vol.23 (11), p.1435-1440 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1440 |
|---|---|
| container_issue | 11 |
| container_start_page | 1435 |
| container_title | Polymers for advanced technologies |
| container_volume | 23 |
| creator | Gorrasi, Giuliana Bredeau, Stéphane Candia, Chiara Di Patimo, Giovanni Pasquale, Salvatore De Dubois, Philippe |
| description | Preparation and analysis of morphology, mechanical, and electrical properties of nanocomposites based on ethylene vinyl acetate (EVA) copolymer and commercial multiwalled carbon nanotubes (CNTs) was achieved. The used techniques for obtaining nanocomposites were the conventional melt‐mixing and the in situ ethylene polymerization/coating reaction, as catalyzed directly from CNT surface, with different polyethylene content (i.e. 55.0% and 66.6%). Nanocomposites were also prepared using crude CNTs. The incorporation in the molten state of such polyethylene surface‐coated CNTs, used as “masterbatch,” in EVA was demonstrated a good strategy for allowing the complete destructuring of the native bundle‐like aggregates, leading to the preparation of polymer nanocomposites with largely improved properties, even at very low nanofiller content. Copyright © 2011 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/pat.2064 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_pat_2064</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>PAT2064</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3034-698855b4ccb9b4cc286d6f03453f1e194a481f8cc5f460f8c9dd422c0320326b3</originalsourceid><addsrcrecordid>eNp1kMlKBDEQhhtRcAUfIUcvcZLu9OZNxxXcwO0Y0umKE013miSjts_hA5tRETwIRdUP9dVf8CfJNiW7lJB0Moiwm5KCLSVrlNQ1pnlFlxeapbikrFxN1r1_IiTu6nIt-ZgK19ge9aK3Yd4AVtoYaBGE2Wigh8mL7kcjJAQRAEk7WDN24PweUs52SPfI6zBHUgRhxvd4-APodxF09A0WzfTjDA_glHWd6CUgMCCDs1javp3LoF_g67203WCjG_jNZEUJ42HrZ24kd8dHt9NTfH51cjbdP8cyIxnDRV1Ved4wKZt60dOqaAsVN3mmKNCaCVZRVUmZK1aQKOq2ZWkqSZbGKppsI9n59pXOeu9A8cHpTriRU8IXafKYJl-kGVH8jb5qA-O_HL_ev_3Lax_g7ZcX7pkXZVbm_OHyhJOLaXp4QG_4ffYJCE2KQg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Gorrasi, Giuliana ; Bredeau, Stéphane ; Candia, Chiara Di ; Patimo, Giovanni ; Pasquale, Salvatore De ; Dubois, Philippe</creator><creatorcontrib>Gorrasi, Giuliana ; Bredeau, Stéphane ; Candia, Chiara Di ; Patimo, Giovanni ; Pasquale, Salvatore De ; Dubois, Philippe</creatorcontrib><description>Preparation and analysis of morphology, mechanical, and electrical properties of nanocomposites based on ethylene vinyl acetate (EVA) copolymer and commercial multiwalled carbon nanotubes (CNTs) was achieved. The used techniques for obtaining nanocomposites were the conventional melt‐mixing and the in situ ethylene polymerization/coating reaction, as catalyzed directly from CNT surface, with different polyethylene content (i.e. 55.0% and 66.6%). Nanocomposites were also prepared using crude CNTs. The incorporation in the molten state of such polyethylene surface‐coated CNTs, used as “masterbatch,” in EVA was demonstrated a good strategy for allowing the complete destructuring of the native bundle‐like aggregates, leading to the preparation of polymer nanocomposites with largely improved properties, even at very low nanofiller content. Copyright © 2011 John Wiley & Sons, Ltd.</description><identifier>ISSN: 1042-7147</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.2064</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>carbon nanotubes ; EVA ; polymerization filling technique</subject><ispartof>Polymers for advanced technologies, 2012-11, Vol.23 (11), p.1435-1440</ispartof><rights>Copyright © 2011 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3034-698855b4ccb9b4cc286d6f03453f1e194a481f8cc5f460f8c9dd422c0320326b3</citedby><cites>FETCH-LOGICAL-c3034-698855b4ccb9b4cc286d6f03453f1e194a481f8cc5f460f8c9dd422c0320326b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpat.2064$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpat.2064$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Gorrasi, Giuliana</creatorcontrib><creatorcontrib>Bredeau, Stéphane</creatorcontrib><creatorcontrib>Candia, Chiara Di</creatorcontrib><creatorcontrib>Patimo, Giovanni</creatorcontrib><creatorcontrib>Pasquale, Salvatore De</creatorcontrib><creatorcontrib>Dubois, Philippe</creatorcontrib><title>Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites</title><title>Polymers for advanced technologies</title><addtitle>Polym. Adv. Technol</addtitle><description>Preparation and analysis of morphology, mechanical, and electrical properties of nanocomposites based on ethylene vinyl acetate (EVA) copolymer and commercial multiwalled carbon nanotubes (CNTs) was achieved. The used techniques for obtaining nanocomposites were the conventional melt‐mixing and the in situ ethylene polymerization/coating reaction, as catalyzed directly from CNT surface, with different polyethylene content (i.e. 55.0% and 66.6%). Nanocomposites were also prepared using crude CNTs. The incorporation in the molten state of such polyethylene surface‐coated CNTs, used as “masterbatch,” in EVA was demonstrated a good strategy for allowing the complete destructuring of the native bundle‐like aggregates, leading to the preparation of polymer nanocomposites with largely improved properties, even at very low nanofiller content. Copyright © 2011 John Wiley & Sons, Ltd.</description><subject>carbon nanotubes</subject><subject>EVA</subject><subject>polymerization filling technique</subject><issn>1042-7147</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kMlKBDEQhhtRcAUfIUcvcZLu9OZNxxXcwO0Y0umKE013miSjts_hA5tRETwIRdUP9dVf8CfJNiW7lJB0Moiwm5KCLSVrlNQ1pnlFlxeapbikrFxN1r1_IiTu6nIt-ZgK19ge9aK3Yd4AVtoYaBGE2Wigh8mL7kcjJAQRAEk7WDN24PweUs52SPfI6zBHUgRhxvd4-APodxF09A0WzfTjDA_glHWd6CUgMCCDs1javp3LoF_g67203WCjG_jNZEUJ42HrZ24kd8dHt9NTfH51cjbdP8cyIxnDRV1Ved4wKZt60dOqaAsVN3mmKNCaCVZRVUmZK1aQKOq2ZWkqSZbGKppsI9n59pXOeu9A8cHpTriRU8IXafKYJl-kGVH8jb5qA-O_HL_ev_3Lax_g7ZcX7pkXZVbm_OHyhJOLaXp4QG_4ffYJCE2KQg</recordid><startdate>201211</startdate><enddate>201211</enddate><creator>Gorrasi, Giuliana</creator><creator>Bredeau, Stéphane</creator><creator>Candia, Chiara Di</creator><creator>Patimo, Giovanni</creator><creator>Pasquale, Salvatore De</creator><creator>Dubois, Philippe</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201211</creationdate><title>Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites</title><author>Gorrasi, Giuliana ; Bredeau, Stéphane ; Candia, Chiara Di ; Patimo, Giovanni ; Pasquale, Salvatore De ; Dubois, Philippe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3034-698855b4ccb9b4cc286d6f03453f1e194a481f8cc5f460f8c9dd422c0320326b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>carbon nanotubes</topic><topic>EVA</topic><topic>polymerization filling technique</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gorrasi, Giuliana</creatorcontrib><creatorcontrib>Bredeau, Stéphane</creatorcontrib><creatorcontrib>Candia, Chiara Di</creatorcontrib><creatorcontrib>Patimo, Giovanni</creatorcontrib><creatorcontrib>Pasquale, Salvatore De</creatorcontrib><creatorcontrib>Dubois, Philippe</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gorrasi, Giuliana</au><au>Bredeau, Stéphane</au><au>Candia, Chiara Di</au><au>Patimo, Giovanni</au><au>Pasquale, Salvatore De</au><au>Dubois, Philippe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites</atitle><jtitle>Polymers for advanced technologies</jtitle><addtitle>Polym. Adv. Technol</addtitle><date>2012-11</date><risdate>2012</risdate><volume>23</volume><issue>11</issue><spage>1435</spage><epage>1440</epage><pages>1435-1440</pages><issn>1042-7147</issn><eissn>1099-1581</eissn><abstract>Preparation and analysis of morphology, mechanical, and electrical properties of nanocomposites based on ethylene vinyl acetate (EVA) copolymer and commercial multiwalled carbon nanotubes (CNTs) was achieved. The used techniques for obtaining nanocomposites were the conventional melt‐mixing and the in situ ethylene polymerization/coating reaction, as catalyzed directly from CNT surface, with different polyethylene content (i.e. 55.0% and 66.6%). Nanocomposites were also prepared using crude CNTs. The incorporation in the molten state of such polyethylene surface‐coated CNTs, used as “masterbatch,” in EVA was demonstrated a good strategy for allowing the complete destructuring of the native bundle‐like aggregates, leading to the preparation of polymer nanocomposites with largely improved properties, even at very low nanofiller content. Copyright © 2011 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pat.2064</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-7147 |
| ispartof | Polymers for advanced technologies, 2012-11, Vol.23 (11), p.1435-1440 |
| issn | 1042-7147 1099-1581 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pat_2064 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | carbon nanotubes EVA polymerization filling technique |
| title | Carbon nanotube-filled ethylene/vinylacetate copolymers: from in situ catalyzed polymerization to high-performance electro-conductive nanocomposites |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T01%3A06%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Carbon%20nanotube-filled%20ethylene/vinylacetate%20copolymers:%20from%20in%20situ%20catalyzed%20polymerization%20to%20high-performance%20electro-conductive%20nanocomposites&rft.jtitle=Polymers%20for%20advanced%20technologies&rft.au=Gorrasi,%20Giuliana&rft.date=2012-11&rft.volume=23&rft.issue=11&rft.spage=1435&rft.epage=1440&rft.pages=1435-1440&rft.issn=1042-7147&rft.eissn=1099-1581&rft_id=info:doi/10.1002/pat.2064&rft_dat=%3Cwiley_cross%3EPAT2064%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |