In-beam ionization by alkali ion attachment applying a two-filament ion source
A simple ion source was constructed for in‐beam ionization by alkali ion attachment. A wire probe covered with sample was placed near an alkali ion emitter prepared from a mixture of silica gel and alkali halides. The ionization of various thermally labile compounds and of mixtures was investigated....
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| Veröffentlicht in: | Organic Mass Spectrometry 1985-04, Vol.20 (4), p.305-309 |
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| container_issue | 4 |
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| container_title | Organic Mass Spectrometry |
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| creator | Schmelzeisen-Redeker, G. Giessmann, U. Röllgen, F. W. |
| description | A simple ion source was constructed for in‐beam ionization by alkali ion attachment. A wire probe covered with sample was placed near an alkali ion emitter prepared from a mixture of silica gel and alkali halides. The ionization of various thermally labile compounds and of mixtures was investigated. Na+ proved to be the most suitable alkali ion for cationization. For monosaccharides experiments revealed the elimination of water upon ionization by Li+ attachment. The experimental set‐up was also examined for measuring the heat of sublimation of organic solids. |
| doi_str_mv | 10.1002/oms.1210200408 |
| format | Article |
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W.</creator><creatorcontrib>Schmelzeisen-Redeker, G. ; Giessmann, U. ; Röllgen, F. W.</creatorcontrib><description>A simple ion source was constructed for in‐beam ionization by alkali ion attachment. A wire probe covered with sample was placed near an alkali ion emitter prepared from a mixture of silica gel and alkali halides. The ionization of various thermally labile compounds and of mixtures was investigated. Na+ proved to be the most suitable alkali ion for cationization. For monosaccharides experiments revealed the elimination of water upon ionization by Li+ attachment. 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| fulltext | fulltext |
| identifier | ISSN: 0030-493X |
| ispartof | Organic Mass Spectrometry, 1985-04, Vol.20 (4), p.305-309 |
| issn | 0030-493X 1096-9888 2376-3884 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_oms_1210200408 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry Exact sciences and technology Mass spectrometry Organic chemistry Reactivity and mechanisms |
| title | In-beam ionization by alkali ion attachment applying a two-filament ion source |
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