Studies in mass spectrometry. III-formation of a common intermediate in the primary fragmentation process of 1-phenylcyclobutene and of 2-phenyl-1,3-butadiene

The mass spectra of the title compounds show peaks corresponding to the primary fragmentation of H, CH3 and (H2 + C2H2). Kinetic study suggests that the molecular ion of 1‐phenylcyclobutene and 2‐phenyl‐1,3‐butadiene loses H and CH3 through formation of a common intermediate. This is confirmed by ap...

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Veröffentlicht in:	Organic Mass Spectrometry 1975-11, Vol.10 (11), p.935-945
Hauptverfasser:	Derocque, Jean-Luc, Jochem, Martin
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Sprache:	eng
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description	The mass spectra of the title compounds show peaks corresponding to the primary fragmentation of H, CH3 and (H2 + C2H2). Kinetic study suggests that the molecular ion of 1‐phenylcyclobutene and 2‐phenyl‐1,3‐butadiene loses H and CH3 through formation of a common intermediate. This is confirmed by appearance potential and ionisation potential measurements, fragmentation of deuterium labelled compounds and the corrected Z values.
doi_str_mv	10.1002/oms.1210101104
format	Article
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title	Studies in mass spectrometry. III-formation of a common intermediate in the primary fragmentation process of 1-phenylcyclobutene and of 2-phenyl-1,3-butadiene
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