The symmetry of the Ion formed by stepwise loss of CO molecules in the mass spectra of p-benzoquinones

The symmetry of the Ion formed by stepwise loss of CO molecules in the mass spectra of p-benzoquinones

Contrary to previous suppositions, it appears that the produced by the loss of 2 CO from para‐benzoquinones passes through the symmetry of not a substituted cyclobutadiene, but rather a substituted tetrahedrane, at least for inert R. The p‐fluoro labeling technique is used to obtain this result.

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Veröffentlicht in:Organic Mass Spectrometry 1968-08, Vol.1 (4), p.537-542
Hauptverfasser: Elwood, Thomas A., Bursey, Maurice M.
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container_title Organic Mass Spectrometry
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creator Elwood, Thomas A.
Bursey, Maurice M.
description Contrary to previous suppositions, it appears that the produced by the loss of 2 CO from para‐benzoquinones passes through the symmetry of not a substituted cyclobutadiene, but rather a substituted tetrahedrane, at least for inert R. The p‐fluoro labeling technique is used to obtain this result.
doi_str_mv 10.1002/oms.1210010407
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title The symmetry of the Ion formed by stepwise loss of CO molecules in the mass spectra of p-benzoquinones
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