Proton and carbon-13 nuclear magnetic resonance studies of substituted pyridines and pyrimidines: VII-The structure of hydroxy- and mercapto- pyridines and pyrimides from J(HH) and J(CH) values
Accurate values of iJ(HH) and iJ(CH) were obtained for a series of hydroxy‐and mercaptopyridines and‐pyrimidines. It is shown that the 3J(CH) values provide a valuable criterion for differentiating aromatic from quinoidal structures, and is an easy method for determining N‐methylation or N‐addition...
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Veröffentlicht in: | Organic Magnetic Resonance 1983-01, Vol.21 (1), p.20-23 |
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container_title | Organic Magnetic Resonance |
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creator | Vitorge, M. C. Chenon, M. T. Coupry, C. Lumbroso-Bader, N. |
description | Accurate values of iJ(HH) and iJ(CH) were obtained for a series of hydroxy‐and mercaptopyridines and‐pyrimidines. It is shown that the 3J(CH) values provide a valuable criterion for differentiating aromatic from quinoidal structures, and is an easy method for determining N‐methylation or N‐addition sites. |
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title | Proton and carbon-13 nuclear magnetic resonance studies of substituted pyridines and pyrimidines: VII-The structure of hydroxy- and mercapto- pyridines and pyrimides from J(HH) and J(CH) values |
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