π-conjugated columnar polyacetylenes prepared with Rh complex catalysts

Highly stereospecific polymerization of monosubstituted acetylenes was carried out using the Rh complex, [Rh(norbornadiene)Cl]2 catalysts. The resulting polyacetylenes were characterized in detail by 1HNMR, ESR, laser Raman, diffuse reflective UV, and wide angle X‐ray diffraction methods. The data s...

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Veröffentlicht in:	Macromolecular symposia. 2003-03, Vol.192 (1), p.75-98
Hauptverfasser:	Masayoshi, Tabata, Takeyuki, Sone, Yasuteru, Mawatari, Daigo, Yonemoto, Atsushi, Miyasaka, Takashi, Fukushima, Yoshikazu, Sadahiro
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysts poly acetylene self-assembly stereospecific polymers WAXS
Online-Zugang:	Volltext
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