Electro-Copolymerization of Layer-by-Layer Deposited Polythiophene and Polycarbazole Precursor Ultrathin Films
The synthesis, layer‐by‐layer deposition, and electro‐copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross‐linking approach towards a highly ordered ultrathin fi...
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| Veröffentlicht in: | Macromolecular rapid communications. 2007-08, Vol.28 (15), p.1522-1527 |
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| container_title | Macromolecular rapid communications. |
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| creator | Waenkaew, Paralee Taranekar, Prasad Phanichphant, Sukon Advincula, Rigoberto C. |
| description | The synthesis, layer‐by‐layer deposition, and electro‐copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross‐linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer‐limited homo‐ and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross‐linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro‐copolymerizability. |
| doi_str_mv | 10.1002/marc.200700217 |
| format | Article |
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The interest is in observing an electrochemical cross‐linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer‐limited homo‐ and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross‐linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro‐copolymerizability.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200700217</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; conjugated polymers ; electropolymerization ; Exact sciences and technology ; layer growth ; LbL films ; Physicochemistry of polymers ; polycarbazole ; Polymerization ; Polymers and radiations ; polythiophene</subject><ispartof>Macromolecular rapid communications., 2007-08, Vol.28 (15), p.1522-1527</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. 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Cross‐linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro‐copolymerizability.</description><subject>Applied sciences</subject><subject>conjugated polymers</subject><subject>electropolymerization</subject><subject>Exact sciences and technology</subject><subject>layer growth</subject><subject>LbL films</subject><subject>Physicochemistry of polymers</subject><subject>polycarbazole</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><subject>polythiophene</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAURSMEEqWwMmdhdPFH0iRjVdqCFKBCVGWzXmxHNaRxZAdB-utxCSpsTO8-65xn6QbBJcEjgjG93oIVI4px4heSHAUDElOCWEaTY58xpYgwNj4Nzpx7xRinEaaDoJ5VSrTWoKlpTNVtldU7aLWpQ1OGOXTKoqJD3yG8UY1xulUyXHq03WjTbFStQqj7FwG2gJ2pVLi0SrxbZ2y4qloLHq3Dua627jw4KaFy6uJnDoPVfPY8vUX54-JuOsmRYFmUoCgWYyh9jJiEREJRJBRkWUicgpKQCppRJpksVRSziFBVkDiWQKjwlEwFGwaj_q6wxjmrSt5Y7QvqOMF83xbft8UPbXnhqhcacAKq0kIttPu10ixmvkPPZT33oSvV_XOV30-epn__QL2rXas-Dy7YNz5OWBLz9cOC4-hlzeYs4zn7Am-Sjkw</recordid><startdate>20070801</startdate><enddate>20070801</enddate><creator>Waenkaew, Paralee</creator><creator>Taranekar, Prasad</creator><creator>Phanichphant, Sukon</creator><creator>Advincula, Rigoberto C.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20070801</creationdate><title>Electro-Copolymerization of Layer-by-Layer Deposited Polythiophene and Polycarbazole Precursor Ultrathin Films</title><author>Waenkaew, Paralee ; Taranekar, Prasad ; Phanichphant, Sukon ; Advincula, Rigoberto C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3947-45c6af39443da7dabb72adfbd08aeda8c2923d3dfe453412eb155da12cadfd8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>conjugated polymers</topic><topic>electropolymerization</topic><topic>Exact sciences and technology</topic><topic>layer growth</topic><topic>LbL films</topic><topic>Physicochemistry of polymers</topic><topic>polycarbazole</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><topic>polythiophene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Waenkaew, Paralee</creatorcontrib><creatorcontrib>Taranekar, Prasad</creatorcontrib><creatorcontrib>Phanichphant, Sukon</creatorcontrib><creatorcontrib>Advincula, Rigoberto C.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Waenkaew, Paralee</au><au>Taranekar, Prasad</au><au>Phanichphant, Sukon</au><au>Advincula, Rigoberto C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electro-Copolymerization of Layer-by-Layer Deposited Polythiophene and Polycarbazole Precursor Ultrathin Films</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2007-08-01</date><risdate>2007</risdate><volume>28</volume><issue>15</issue><spage>1522</spage><epage>1527</epage><pages>1522-1527</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The synthesis, layer‐by‐layer deposition, and electro‐copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross‐linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer‐limited homo‐ and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. 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| ispartof | Macromolecular rapid communications., 2007-08, Vol.28 (15), p.1522-1527 |
| issn | 1022-1336 1521-3927 |
| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | Applied sciences conjugated polymers electropolymerization Exact sciences and technology layer growth LbL films Physicochemistry of polymers polycarbazole Polymerization Polymers and radiations polythiophene |
| title | Electro-Copolymerization of Layer-by-Layer Deposited Polythiophene and Polycarbazole Precursor Ultrathin Films |
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