Microwave-Assisted Synthesis of Associative Hydrogels
In the present paper, the microwave (MW)‐assisted synthesis of hydrogel forming polymers based on poly(acrylic acid) (1) is described. The polymer analogous condensation reaction between adamantyl moieties bearing free amino groups and poly(acrylic acid) (1) was carried out simply by mixing both com...
Gespeichert in:
| Veröffentlicht in: | Macromolecular rapid communications. 2007-06, Vol.28 (11), p.1265-1269 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1269 |
|---|---|
| container_issue | 11 |
| container_start_page | 1265 |
| container_title | Macromolecular rapid communications. |
| container_volume | 28 |
| creator | Kretschmann, Oliver Schmitz, Sarah Ritter, Helmut |
| description | In the present paper, the microwave (MW)‐assisted synthesis of hydrogel forming polymers based on poly(acrylic acid) (1) is described. The polymer analogous condensation reaction between adamantyl moieties bearing free amino groups and poly(acrylic acid) (1) was carried out simply by mixing both components and subsequent use of MW protocol. The mixture was irradiated for 20 min without the addition of solvents or coupling agents. Aqueous solutions of the sodium salts of the obtained hydrophobically modified poly(acrylic acid)s showed a very high viscosity due to the intermolecular association of the hydrophobic side chains and the resulting formation of physical networks. By the addition of randomly methylated β‐cyclodextrin (RAMEB), the rheology of these systems could be influenced significantly. |
| doi_str_mv | 10.1002/marc.200700117 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_marc_200700117</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_8BB978X0_9</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3577-c05f9f8b4b187983109ad097b6c60359c6a784ca72e0d329d99b2d05920a0c4a3</originalsourceid><addsrcrecordid>eNqFkD1PwzAQhi0EEqWwMmdhTDnbcWyPbQUtUgsSH4LNchwHDKGp7Kgl_x5XQYWN6T50z3v3HkLnGEYYgFx-am9GBIADYMwP0AAzglMqCT-MORCSYkrzY3QSwjsAiAzIALGlM77Z6o1NxyG40NoyeehW7ZuNRdJUSew2xunWbWwy70rfvNo6nKKjStfBnv3EIXq6vnqcztPF3exmOl6khjLOUwOskpUosgILLgXFIHUJkhe5yYEyaXLNRWY0JxZKSmQpZUFKYJKABpNpOkSjXjfeGIK3lVp7F312CoPamVY702pvOgIXPbDWwei68nplXPilhAAuchbnZD-3dbXt_lFVy_H99O-OtGd33_ras9p_qJxTztTz7UyJyURy8QJK0m9X_HZa</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Microwave-Assisted Synthesis of Associative Hydrogels</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Kretschmann, Oliver ; Schmitz, Sarah ; Ritter, Helmut</creator><creatorcontrib>Kretschmann, Oliver ; Schmitz, Sarah ; Ritter, Helmut</creatorcontrib><description>In the present paper, the microwave (MW)‐assisted synthesis of hydrogel forming polymers based on poly(acrylic acid) (1) is described. The polymer analogous condensation reaction between adamantyl moieties bearing free amino groups and poly(acrylic acid) (1) was carried out simply by mixing both components and subsequent use of MW protocol. The mixture was irradiated for 20 min without the addition of solvents or coupling agents. Aqueous solutions of the sodium salts of the obtained hydrophobically modified poly(acrylic acid)s showed a very high viscosity due to the intermolecular association of the hydrophobic side chains and the resulting formation of physical networks. By the addition of randomly methylated β‐cyclodextrin (RAMEB), the rheology of these systems could be influenced significantly.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200700117</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; chain ; cyclodextrin ; Exact sciences and technology ; hydrogels ; microwave ; Organic polymers ; physical network ; Physicochemistry of polymers ; polymer analogs reaction ; Properties and characterization ; Solution and gel properties</subject><ispartof>Macromolecular rapid communications., 2007-06, Vol.28 (11), p.1265-1269</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3577-c05f9f8b4b187983109ad097b6c60359c6a784ca72e0d329d99b2d05920a0c4a3</citedby><cites>FETCH-LOGICAL-c3577-c05f9f8b4b187983109ad097b6c60359c6a784ca72e0d329d99b2d05920a0c4a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.200700117$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.200700117$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18807865$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kretschmann, Oliver</creatorcontrib><creatorcontrib>Schmitz, Sarah</creatorcontrib><creatorcontrib>Ritter, Helmut</creatorcontrib><title>Microwave-Assisted Synthesis of Associative Hydrogels</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>In the present paper, the microwave (MW)‐assisted synthesis of hydrogel forming polymers based on poly(acrylic acid) (1) is described. The polymer analogous condensation reaction between adamantyl moieties bearing free amino groups and poly(acrylic acid) (1) was carried out simply by mixing both components and subsequent use of MW protocol. The mixture was irradiated for 20 min without the addition of solvents or coupling agents. Aqueous solutions of the sodium salts of the obtained hydrophobically modified poly(acrylic acid)s showed a very high viscosity due to the intermolecular association of the hydrophobic side chains and the resulting formation of physical networks. By the addition of randomly methylated β‐cyclodextrin (RAMEB), the rheology of these systems could be influenced significantly.</description><subject>Applied sciences</subject><subject>chain</subject><subject>cyclodextrin</subject><subject>Exact sciences and technology</subject><subject>hydrogels</subject><subject>microwave</subject><subject>Organic polymers</subject><subject>physical network</subject><subject>Physicochemistry of polymers</subject><subject>polymer analogs reaction</subject><subject>Properties and characterization</subject><subject>Solution and gel properties</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhi0EEqWwMmdhTDnbcWyPbQUtUgsSH4LNchwHDKGp7Kgl_x5XQYWN6T50z3v3HkLnGEYYgFx-am9GBIADYMwP0AAzglMqCT-MORCSYkrzY3QSwjsAiAzIALGlM77Z6o1NxyG40NoyeehW7ZuNRdJUSew2xunWbWwy70rfvNo6nKKjStfBnv3EIXq6vnqcztPF3exmOl6khjLOUwOskpUosgILLgXFIHUJkhe5yYEyaXLNRWY0JxZKSmQpZUFKYJKABpNpOkSjXjfeGIK3lVp7F312CoPamVY702pvOgIXPbDWwei68nplXPilhAAuchbnZD-3dbXt_lFVy_H99O-OtGd33_ras9p_qJxTztTz7UyJyURy8QJK0m9X_HZa</recordid><startdate>20070601</startdate><enddate>20070601</enddate><creator>Kretschmann, Oliver</creator><creator>Schmitz, Sarah</creator><creator>Ritter, Helmut</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20070601</creationdate><title>Microwave-Assisted Synthesis of Associative Hydrogels</title><author>Kretschmann, Oliver ; Schmitz, Sarah ; Ritter, Helmut</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3577-c05f9f8b4b187983109ad097b6c60359c6a784ca72e0d329d99b2d05920a0c4a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>chain</topic><topic>cyclodextrin</topic><topic>Exact sciences and technology</topic><topic>hydrogels</topic><topic>microwave</topic><topic>Organic polymers</topic><topic>physical network</topic><topic>Physicochemistry of polymers</topic><topic>polymer analogs reaction</topic><topic>Properties and characterization</topic><topic>Solution and gel properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kretschmann, Oliver</creatorcontrib><creatorcontrib>Schmitz, Sarah</creatorcontrib><creatorcontrib>Ritter, Helmut</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kretschmann, Oliver</au><au>Schmitz, Sarah</au><au>Ritter, Helmut</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microwave-Assisted Synthesis of Associative Hydrogels</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2007-06-01</date><risdate>2007</risdate><volume>28</volume><issue>11</issue><spage>1265</spage><epage>1269</epage><pages>1265-1269</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>In the present paper, the microwave (MW)‐assisted synthesis of hydrogel forming polymers based on poly(acrylic acid) (1) is described. The polymer analogous condensation reaction between adamantyl moieties bearing free amino groups and poly(acrylic acid) (1) was carried out simply by mixing both components and subsequent use of MW protocol. The mixture was irradiated for 20 min without the addition of solvents or coupling agents. Aqueous solutions of the sodium salts of the obtained hydrophobically modified poly(acrylic acid)s showed a very high viscosity due to the intermolecular association of the hydrophobic side chains and the resulting formation of physical networks. By the addition of randomly methylated β‐cyclodextrin (RAMEB), the rheology of these systems could be influenced significantly.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200700117</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1336 |
| ispartof | Macromolecular rapid communications., 2007-06, Vol.28 (11), p.1265-1269 |
| issn | 1022-1336 1521-3927 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_marc_200700117 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences chain cyclodextrin Exact sciences and technology hydrogels microwave Organic polymers physical network Physicochemistry of polymers polymer analogs reaction Properties and characterization Solution and gel properties |
| title | Microwave-Assisted Synthesis of Associative Hydrogels |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-23T03%3A24%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Microwave-Assisted%20Synthesis%20of%20Associative%20Hydrogels&rft.jtitle=Macromolecular%20rapid%20communications.&rft.au=Kretschmann,%20Oliver&rft.date=2007-06-01&rft.volume=28&rft.issue=11&rft.spage=1265&rft.epage=1269&rft.pages=1265-1269&rft.issn=1022-1336&rft.eissn=1521-3927&rft_id=info:doi/10.1002/marc.200700117&rft_dat=%3Cistex_cross%3Eark_67375_WNG_8BB978X0_9%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |