Emulsion-Induced Ordered Microporous Films Based on Micelles of Amphiphilic Poly(ethylene oxide)-block-Poly(methyl methacrylate) Diblock Copolymers
Well‐defined PEO‐b‐PMMA was prepared, initiated by macroinitiator PEO‐Br, by means of ATRP, where esterification of the terminal hydroxyl group of PEO with 2‐bromoisobutyryl bromide yielded a macroinitiator PEO‐Br. Highly ordered microporous films (hexagonal pattern) were constructed by emulsion mic...
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| Veröffentlicht in: | Macromolecular rapid communications. 2007-04, Vol.28 (7), p.882-887 |
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| container_end_page | 887 |
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| container_title | Macromolecular rapid communications. |
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| creator | Ishizu, Koji Makino, Masataka Uchida, Satoshi |
| description | Well‐defined PEO‐b‐PMMA was prepared, initiated by macroinitiator PEO‐Br, by means of ATRP, where esterification of the terminal hydroxyl group of PEO with 2‐bromoisobutyryl bromide yielded a macroinitiator PEO‐Br. Highly ordered microporous films (hexagonal pattern) were constructed by emulsion micelles of such amphiphilic diblock copolymer formed from a solution with CHCl3/H2O/THF = 100:5:10 (v/v). We also constructed the microporous films using diblock copolymer by the current water‐assisted method. |
| doi_str_mv | 10.1002/marc.200600828 |
| format | Article |
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Highly ordered microporous films (hexagonal pattern) were constructed by emulsion micelles of such amphiphilic diblock copolymer formed from a solution with CHCl3/H2O/THF = 100:5:10 (v/v). We also constructed the microporous films using diblock copolymer by the current water‐assisted method.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200600828</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>amphiphilic diblock copolymer ; Applied sciences ; ATRP ; emulsion micelle ; Exact sciences and technology ; Fibers and threads ; Forms of application and semi-finished materials ; NMR ; ordered microporous pattern ; Organic polymers ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Technology of polymers</subject><ispartof>Macromolecular rapid communications., 2007-04, Vol.28 (7), p.882-887</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. 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We also constructed the microporous films using diblock copolymer by the current water‐assisted method.</description><subject>amphiphilic diblock copolymer</subject><subject>Applied sciences</subject><subject>ATRP</subject><subject>emulsion micelle</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Forms of application and semi-finished materials</subject><subject>NMR</subject><subject>ordered microporous pattern</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Technology of polymers</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQjBBIPK-cfUGCg4tjJ3F8LIXyEAWEQHCzHGcrDE5c2a0g38EP47QIuCGtNGvPzK52kmQ_JYOUEHrcKK8HlJCCkJKWa8lWmtMUM0H5euwJpThlrNhMtkN4JVGTEbqVfJ41CxuMa_FlWy801OjW1-AjToz2bua8WwQ0NrYJ6ESF-O_angJrISA3RcNm9mJiWaPRnbPdIcxfOgstIPdhajjClXX6DS-pZsmhHpT2nVVzOEKnZqlAo7jMdg34sJtsTJUNsPeNO8nj-OxhdIGvb88vR8NrrJngJWaZUKKK52lRAeOCFFnVv-uCVqmqc6LKnGqtOc05F1lWVaBTIvIcdJ1lWrCdZLCaGw8NwcNUzryJKXYyJbKPVPaRyp9Io-FgZZipoJWdetVqE35dZcE5Y3nUiZXu3Vjo_pkqJ8P70d8deOU1YQ4fP17l32TBGc_l0825HJ-Qq8mzeJZP7AuamZnp</recordid><startdate>20070402</startdate><enddate>20070402</enddate><creator>Ishizu, Koji</creator><creator>Makino, Masataka</creator><creator>Uchida, Satoshi</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20070402</creationdate><title>Emulsion-Induced Ordered Microporous Films Based on Micelles of Amphiphilic Poly(ethylene oxide)-block-Poly(methyl methacrylate) Diblock Copolymers</title><author>Ishizu, Koji ; Makino, Masataka ; Uchida, Satoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3978-349a9b927c9be379064b9b92d62b1ad50a852ccc72577944bbec10955ecd44c93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>amphiphilic diblock copolymer</topic><topic>Applied sciences</topic><topic>ATRP</topic><topic>emulsion micelle</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Forms of application and semi-finished materials</topic><topic>NMR</topic><topic>ordered microporous pattern</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ishizu, Koji</creatorcontrib><creatorcontrib>Makino, Masataka</creatorcontrib><creatorcontrib>Uchida, Satoshi</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ishizu, Koji</au><au>Makino, Masataka</au><au>Uchida, Satoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Emulsion-Induced Ordered Microporous Films Based on Micelles of Amphiphilic Poly(ethylene oxide)-block-Poly(methyl methacrylate) Diblock Copolymers</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2007-04-02</date><risdate>2007</risdate><volume>28</volume><issue>7</issue><spage>882</spage><epage>887</epage><pages>882-887</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>Well‐defined PEO‐b‐PMMA was prepared, initiated by macroinitiator PEO‐Br, by means of ATRP, where esterification of the terminal hydroxyl group of PEO with 2‐bromoisobutyryl bromide yielded a macroinitiator PEO‐Br. Highly ordered microporous films (hexagonal pattern) were constructed by emulsion micelles of such amphiphilic diblock copolymer formed from a solution with CHCl3/H2O/THF = 100:5:10 (v/v). We also constructed the microporous films using diblock copolymer by the current water‐assisted method.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200600828</doi><tpages>6</tpages></addata></record> |
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| ispartof | Macromolecular rapid communications., 2007-04, Vol.28 (7), p.882-887 |
| issn | 1022-1336 1521-3927 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | amphiphilic diblock copolymer Applied sciences ATRP emulsion micelle Exact sciences and technology Fibers and threads Forms of application and semi-finished materials NMR ordered microporous pattern Organic polymers Physicochemistry of polymers Polymer industry, paints, wood Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Technology of polymers |
| title | Emulsion-Induced Ordered Microporous Films Based on Micelles of Amphiphilic Poly(ethylene oxide)-block-Poly(methyl methacrylate) Diblock Copolymers |
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