Surviving Radicals: Promises of a Microwave Effect on Miniemulsion Polymerization for Technical Processes

Rapid heating in a microwave oven has unexpected effects on free radical miniemulsion polymerization: After a temperature pulse of less than 20 s, ultra‐high molecular weight polystyrene was yielded at a conversion larger than 40%. These results may be explained with the model of “surviving radicals...

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Veröffentlicht in:	Macromolecular rapid communications. 2007-02, Vol.28 (4), p.428-436
Hauptverfasser:	Holtze, Christian, Tauer, Klaus
Format:	Artikel
Sprache:	eng
Schlagworte:	continuous tube reactor free-radical polymerization microwave effect miniemulsion polymerization polystyrene surviving radicals
Online-Zugang:	Volltext
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