Lewis Acid-Induced N-Methyleneamines as Initiators in the Synthesis of Secondary Amine-Terminated Polymers
The cationic polymerization of poly(tert‐butyl vinyl ether) using N‐methyleneamine equivalents derived from a Lewis acid/1,3,5‐trimethylhexahydro‐1,3,5‐triazine (TMTA) co‐initiating system is reported. The resulting polymers possessed secondary amine functionality at the chain terminus, verified by...
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| Veröffentlicht in: | Macromolecular rapid communications. 2006-09, Vol.27 (18), p.1578-1583 |
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| container_title | Macromolecular rapid communications. |
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| creator | McKnight, Jeffrey N. Tillman, Eric S. Sarry, Louis R. |
| description | The cationic polymerization of poly(tert‐butyl vinyl ether) using N‐methyleneamine equivalents derived from a Lewis acid/1,3,5‐trimethylhexahydro‐1,3,5‐triazine (TMTA) co‐initiating system is reported. The resulting polymers possessed secondary amine functionality at the chain terminus, verified by derivatization with 4‐chloro‐7‐nitrobenzo‐2‐oxa‐1,3‐diazole (NBD‐Cl) and subsequent analysis with GPC‐UV (470 nm) and 1H NMR.
Use of N‐methyleneamine equivalents lacking aryl substituents to afford amine‐terminated poly(tert‐butyl vinyl ether). |
| doi_str_mv | 10.1002/marc.200600336 |
| format | Article |
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Use of N‐methyleneamine equivalents lacking aryl substituents to afford amine‐terminated poly(tert‐butyl vinyl ether).</description><subject>Applied sciences</subject><subject>cationic polymerization</subject><subject>Exact sciences and technology</subject><subject>functionalization of polymers</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(vinyl ethers)</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhhdRUKtXz7l4TE02u8nusRathbZ-tCB4CWkyodHtbklW6v57UyrVm6d3GOZ5B54kuaKkTwlJb9bK635KCCeEMX6UnNE8pZiVqTiOM0lTTOP-NDkP4Z0QUmQkPUveJ7B1AQ20M3hcm08NBs3wFNpVV0ENau1qCEgFNK5d61Tb-IBcjdoVoHlXxwiRbiyag25qo3yHBjsEL8DHVG2se2qqbg0-XCQnVlUBLn-ylyzu7xbDBzx5HI2HgwnWLBccZ5xavRQ0Y4bwXBhT0gKWBgpjeV6I0gpFs9ICEYaCNZkqciFElvEyX1pKWC_p72u1b0LwYOXGu-imk5TInSi5EyUPoiJwvQc2KmhVWa9q7cIvVdCcF7yMd-X-busq6P5pldPBy_DvD7xnXWjh68Aq_yG5YCKXr7ORTG_5G3vmXFL2DTsTibg</recordid><startdate>20060922</startdate><enddate>20060922</enddate><creator>McKnight, Jeffrey N.</creator><creator>Tillman, Eric S.</creator><creator>Sarry, Louis R.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060922</creationdate><title>Lewis Acid-Induced N-Methyleneamines as Initiators in the Synthesis of Secondary Amine-Terminated Polymers</title><author>McKnight, Jeffrey N. ; Tillman, Eric S. ; Sarry, Louis R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3576-461fcb7143d0657dd918ebde8df65879f7a149fe07d1efd4a8577744695bf103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>cationic polymerization</topic><topic>Exact sciences and technology</topic><topic>functionalization of polymers</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(vinyl ethers)</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McKnight, Jeffrey N.</creatorcontrib><creatorcontrib>Tillman, Eric S.</creatorcontrib><creatorcontrib>Sarry, Louis R.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>McKnight, Jeffrey N.</au><au>Tillman, Eric S.</au><au>Sarry, Louis R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lewis Acid-Induced N-Methyleneamines as Initiators in the Synthesis of Secondary Amine-Terminated Polymers</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2006-09-22</date><risdate>2006</risdate><volume>27</volume><issue>18</issue><spage>1578</spage><epage>1583</epage><pages>1578-1583</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The cationic polymerization of poly(tert‐butyl vinyl ether) using N‐methyleneamine equivalents derived from a Lewis acid/1,3,5‐trimethylhexahydro‐1,3,5‐triazine (TMTA) co‐initiating system is reported. The resulting polymers possessed secondary amine functionality at the chain terminus, verified by derivatization with 4‐chloro‐7‐nitrobenzo‐2‐oxa‐1,3‐diazole (NBD‐Cl) and subsequent analysis with GPC‐UV (470 nm) and 1H NMR.
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| ispartof | Macromolecular rapid communications., 2006-09, Vol.27 (18), p.1578-1583 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1002_marc_200600336 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences cationic polymerization Exact sciences and technology functionalization of polymers Organic polymers Physicochemistry of polymers poly(vinyl ethers) Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Lewis Acid-Induced N-Methyleneamines as Initiators in the Synthesis of Secondary Amine-Terminated Polymers |
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