Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion
The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerization which was initiated wit...
Gespeichert in:
| Veröffentlicht in: | Macromolecular rapid communications. 2005-04, Vol.26 (8), p.592-596 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 596 |
|---|---|
| container_issue | 8 |
| container_start_page | 592 |
| container_title | Macromolecular rapid communications. |
| container_volume | 26 |
| creator | Simms, Ryan W. Davis, Thomas P. Cunningham, Michael F. |
| description | The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerization which was initiated with either of the water‐soluble initiators 2,2′‐azobis{2‐[1‐(2‐hydroxyethyl)‐2‐imidazolin‐2‐yl]propane} dihydrochloride (VA‐060) or 2,2′‐azobis[2‐(2‐dimidazolin‐2‐yl)propane] dihydrochloride (VA‐044). The polymerizations exhibit living characteristics, demonstrated by the evolution of molecular weight distributions. The formulation of the miniemulsion produced stable latexes with no coagulum.
The number‐average molecular weight and PDI as a function of monomer conversion for the RAFT miniemulsion polymerization of vinyl acetate. |
| doi_str_mv | 10.1002/marc.200400652 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_marc_200400652</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_V7GJC9NW_K</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3572-f1d5e49289d75a992672a7a77e58891436284be1f120191f0e1c6ea8aafe24293</originalsourceid><addsrcrecordid>eNqFkD1PwzAQhiMEEqWwMnthTLHPiR2PVQTlo4WqgpbNOhIbDGlaxeEj_HpSBRU2prvhfd7TPUFwzOiAUQqnS6yyAVAaUSpi2Al6LAYWcgVyt90pQMg4F_vBgfcvlNIkotALpg9Y1s9Ym3BictfOnIzduyufyAxzl2FBpquiWZrKfWHtViVZWTJ3ZVOQYWbqNk9cSSaudGb5Vvg2cBjsWSy8OfqZ_eD-_OwuvQjHt6PLdDgOMx5LCC3LYxMpSFQuY1QKhASUKKWJk0SxiAtIokfDLAPKFLPUsEwYTBCtgQgU7weDrjerVt5Xxup15VoFjWZUb3zojQ-99dECJx2wRt_-ZSssM-d_KSEjJvimWHW5D1eY5p9WPRnO0r83wo51vjafWxarVy0kl7Fe3Iz0XI6uUnWz0Nf8G2a0gEQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion</title><source>Wiley Online Library All Journals</source><creator>Simms, Ryan W. ; Davis, Thomas P. ; Cunningham, Michael F.</creator><creatorcontrib>Simms, Ryan W. ; Davis, Thomas P. ; Cunningham, Michael F.</creatorcontrib><description>The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerization which was initiated with either of the water‐soluble initiators 2,2′‐azobis{2‐[1‐(2‐hydroxyethyl)‐2‐imidazolin‐2‐yl]propane} dihydrochloride (VA‐060) or 2,2′‐azobis[2‐(2‐dimidazolin‐2‐yl)propane] dihydrochloride (VA‐044). The polymerizations exhibit living characteristics, demonstrated by the evolution of molecular weight distributions. The formulation of the miniemulsion produced stable latexes with no coagulum.
The number‐average molecular weight and PDI as a function of monomer conversion for the RAFT miniemulsion polymerization of vinyl acetate.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200400652</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; controlled polymerization ; Exact sciences and technology ; living polymerization ; macromolecular design via interchange of xanthates (MADIX) ; miniemulsion ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; reversible addition fragmentation chain transfer (RAFT)</subject><ispartof>Macromolecular rapid communications., 2005-04, Vol.26 (8), p.592-596</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3572-f1d5e49289d75a992672a7a77e58891436284be1f120191f0e1c6ea8aafe24293</citedby><cites>FETCH-LOGICAL-c3572-f1d5e49289d75a992672a7a77e58891436284be1f120191f0e1c6ea8aafe24293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.200400652$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.200400652$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16741639$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Simms, Ryan W.</creatorcontrib><creatorcontrib>Davis, Thomas P.</creatorcontrib><creatorcontrib>Cunningham, Michael F.</creatorcontrib><title>Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerization which was initiated with either of the water‐soluble initiators 2,2′‐azobis{2‐[1‐(2‐hydroxyethyl)‐2‐imidazolin‐2‐yl]propane} dihydrochloride (VA‐060) or 2,2′‐azobis[2‐(2‐dimidazolin‐2‐yl)propane] dihydrochloride (VA‐044). The polymerizations exhibit living characteristics, demonstrated by the evolution of molecular weight distributions. The formulation of the miniemulsion produced stable latexes with no coagulum.
The number‐average molecular weight and PDI as a function of monomer conversion for the RAFT miniemulsion polymerization of vinyl acetate.</description><subject>Applied sciences</subject><subject>controlled polymerization</subject><subject>Exact sciences and technology</subject><subject>living polymerization</subject><subject>macromolecular design via interchange of xanthates (MADIX)</subject><subject>miniemulsion</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>reversible addition fragmentation chain transfer (RAFT)</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhiMEEqWwMnthTLHPiR2PVQTlo4WqgpbNOhIbDGlaxeEj_HpSBRU2prvhfd7TPUFwzOiAUQqnS6yyAVAaUSpi2Al6LAYWcgVyt90pQMg4F_vBgfcvlNIkotALpg9Y1s9Ym3BictfOnIzduyufyAxzl2FBpquiWZrKfWHtViVZWTJ3ZVOQYWbqNk9cSSaudGb5Vvg2cBjsWSy8OfqZ_eD-_OwuvQjHt6PLdDgOMx5LCC3LYxMpSFQuY1QKhASUKKWJk0SxiAtIokfDLAPKFLPUsEwYTBCtgQgU7weDrjerVt5Xxup15VoFjWZUb3zojQ-99dECJx2wRt_-ZSssM-d_KSEjJvimWHW5D1eY5p9WPRnO0r83wo51vjafWxarVy0kl7Fe3Iz0XI6uUnWz0Nf8G2a0gEQ</recordid><startdate>20050422</startdate><enddate>20050422</enddate><creator>Simms, Ryan W.</creator><creator>Davis, Thomas P.</creator><creator>Cunningham, Michael F.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050422</creationdate><title>Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion</title><author>Simms, Ryan W. ; Davis, Thomas P. ; Cunningham, Michael F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3572-f1d5e49289d75a992672a7a77e58891436284be1f120191f0e1c6ea8aafe24293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>controlled polymerization</topic><topic>Exact sciences and technology</topic><topic>living polymerization</topic><topic>macromolecular design via interchange of xanthates (MADIX)</topic><topic>miniemulsion</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>reversible addition fragmentation chain transfer (RAFT)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Simms, Ryan W.</creatorcontrib><creatorcontrib>Davis, Thomas P.</creatorcontrib><creatorcontrib>Cunningham, Michael F.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Simms, Ryan W.</au><au>Davis, Thomas P.</au><au>Cunningham, Michael F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2005-04-22</date><risdate>2005</risdate><volume>26</volume><issue>8</issue><spage>592</spage><epage>596</epage><pages>592-596</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerization which was initiated with either of the water‐soluble initiators 2,2′‐azobis{2‐[1‐(2‐hydroxyethyl)‐2‐imidazolin‐2‐yl]propane} dihydrochloride (VA‐060) or 2,2′‐azobis[2‐(2‐dimidazolin‐2‐yl)propane] dihydrochloride (VA‐044). The polymerizations exhibit living characteristics, demonstrated by the evolution of molecular weight distributions. The formulation of the miniemulsion produced stable latexes with no coagulum.
The number‐average molecular weight and PDI as a function of monomer conversion for the RAFT miniemulsion polymerization of vinyl acetate.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200400652</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1336 |
| ispartof | Macromolecular rapid communications., 2005-04, Vol.26 (8), p.592-596 |
| issn | 1022-1336 1521-3927 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_marc_200400652 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences controlled polymerization Exact sciences and technology living polymerization macromolecular design via interchange of xanthates (MADIX) miniemulsion Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts reversible addition fragmentation chain transfer (RAFT) |
| title | Xanthate-Mediated Living Radical Polymerization of Vinyl Acetate in Miniemulsion |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T20%3A56%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Xanthate-Mediated%20Living%20Radical%20Polymerization%20of%20Vinyl%20Acetate%20in%20Miniemulsion&rft.jtitle=Macromolecular%20rapid%20communications.&rft.au=Simms,%20Ryan%20W.&rft.date=2005-04-22&rft.volume=26&rft.issue=8&rft.spage=592&rft.epage=596&rft.pages=592-596&rft.issn=1022-1336&rft.eissn=1521-3927&rft_id=info:doi/10.1002/marc.200400652&rft_dat=%3Cistex_cross%3Eark_67375_WNG_V7GJC9NW_K%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |