Polymerization of Aniline by Auric Acid: Formation of Gold Decorated Polyaniline Nanoballs

We report a new method for the preparation of polyaniline nanoballs by using HAuCl4 as an oxidizing agent. During the reaction, aniline is oxidized and forms polyaniline whilst the hydrogen tetrachloroaurate is reduced and forms gold nanoparticles. These gold nanoparticles are found to decorate the...

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Veröffentlicht in:Macromolecular rapid communications. 2005-02, Vol.26 (4), p.232-235
Hauptverfasser: Mallick, Kaushik, Witcomb, Mike J., Dinsmore, Andy, Scurrell, Mike S.
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container_title Macromolecular rapid communications.
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creator Mallick, Kaushik
Witcomb, Mike J.
Dinsmore, Andy
Scurrell, Mike S.
description We report a new method for the preparation of polyaniline nanoballs by using HAuCl4 as an oxidizing agent. During the reaction, aniline is oxidized and forms polyaniline whilst the hydrogen tetrachloroaurate is reduced and forms gold nanoparticles. These gold nanoparticles are found to decorate the nanoballs. The resultant precipitate and corresponding TEM image of the gold‐nanoparticle covered polyaniline nanoball.
doi_str_mv 10.1002/marc.200400513
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subjects gold nanoparticle
in-situ synthesis
phase-transfer catalysis
polyaniline
title Polymerization of Aniline by Auric Acid: Formation of Gold Decorated Polyaniline Nanoballs
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