Poly(pyrazinoquinoxaline)s: New n-Type Conjugated Polymers That Exhibit Highly Reversible Reduction and High Electron Affinity

The pyrazinoquinoxaline‐based conjugated polymers poly(2,7‐diphenylpyrazino(2,3‐g)quinoxaline‐3,8‐diyl‐1,4‐phenylene) (PZQP) and poly(2,7‐diphenylpyrazino(2,3‐g)quinoxaline‐3,8‐diyl‐2,5‐thiophene) (PZQT) have been synthesized and characterized. PZQP and PZQT have optical band gaps of 2.44 and 1.76 e...

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Veröffentlicht in:	Macromolecular rapid communications. 2004-11, Vol.25 (21), p.1829-1834
Hauptverfasser:	Zhu, Yan, Yen, Cheng-Tyng, Jenekhe, Samson A., Chen, Wen-Chang
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences conjugated polymers density functional theory electron affinity Exact sciences and technology Organic polymers Physicochemistry of polymers poly(pyrazinoquinoxaline) Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts synthesis
Online-Zugang:	Volltext
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