Stimuli-Responsive Semi-Fluorinated Polymer Brushes on Porous Silica Substrates

A diblock copolymer brush consisting of poly(methyl acrylate)‐block‐poly(pentafluoropropyl acrylate) (Si/SiO2//PMA‐b‐PPFA) was synthesized on a porous silica substrate. The brush was exposed to selective solvents, as well as thermal treatments, to induce a surface rearrangement. The rearrangement re...

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Veröffentlicht in:	Macromolecular rapid communications. 2004-07, Vol.25 (14), p.1298-1302
Hauptverfasser:	Granville, Anthony M., Brittain, William J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences atom transfer radical polymerization (ATRP) Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers polymer brushes Preparation, kinetics, thermodynamics, mechanism and catalysts stimuli-sensitive polymers
Online-Zugang:	Volltext
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