Cationic Polymerization of 3-Ethyl-3-hydroxymethyloxetane in an Ionic Liquid
Cationic ring‐opening polymerization of 3‐ethyl‐3‐hydroxymethyloxetane (EOX) in a neutral ionic liquid (1‐butyl‐3‐methylimidazolium tetrafluoroborate, [bmim][BF4]) leading to a multihydroxyl, branched polyether proceeds readily to nearly quantitative conversion. Because of the relatively high polari...
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| Veröffentlicht in: | Macromolecular rapid communications. 2004-04, Vol.25 (8), p.878-881 |
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| creator | Biedroń, Tadeusz Bednarek, Melania Kubisa, Przemysław |
| description | Cationic ring‐opening polymerization of 3‐ethyl‐3‐hydroxymethyloxetane (EOX) in a neutral ionic liquid (1‐butyl‐3‐methylimidazolium tetrafluoroborate, [bmim][BF4]) leading to a multihydroxyl, branched polyether proceeds readily to nearly quantitative conversion. Because of the relatively high polarity of ionic liquids, intermolecular hydrogen bonding leading to the formation of aggregates is reduced considerably. On the other hand, intramolecular hydrogen bonding facilitating intramolecular chain transfer is not significantly affected and the molecular weights of polymers are in the same range as those obtained in bulk polymerization or polymerization in organic solvents. |
| doi_str_mv | 10.1002/marc.200300294 |
| format | Article |
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Because of the relatively high polarity of ionic liquids, intermolecular hydrogen bonding leading to the formation of aggregates is reduced considerably. On the other hand, intramolecular hydrogen bonding facilitating intramolecular chain transfer is not significantly affected and the molecular weights of polymers are in the same range as those obtained in bulk polymerization or polymerization in organic solvents.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200300294</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; branched polyethers ; cationic polymerization ; Exact sciences and technology ; ionic liquid ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Macromolecular rapid communications., 2004-04, Vol.25 (8), p.878-881</ispartof><rights>Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3554-b747a9443430d8b64d41167dbfc01fc6d4c891dd170659291d0c1ac71d23b5a43</citedby><cites>FETCH-LOGICAL-c3554-b747a9443430d8b64d41167dbfc01fc6d4c891dd170659291d0c1ac71d23b5a43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.200300294$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15725410$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Bednarek, Melania</creatorcontrib><creatorcontrib>Kubisa, Przemysław</creatorcontrib><title>Cationic Polymerization of 3-Ethyl-3-hydroxymethyloxetane in an Ionic Liquid</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>Cationic ring‐opening polymerization of 3‐ethyl‐3‐hydroxymethyloxetane (EOX) in a neutral ionic liquid (1‐butyl‐3‐methylimidazolium tetrafluoroborate, [bmim][BF4]) leading to a multihydroxyl, branched polyether proceeds readily to nearly quantitative conversion. Because of the relatively high polarity of ionic liquids, intermolecular hydrogen bonding leading to the formation of aggregates is reduced considerably. On the other hand, intramolecular hydrogen bonding facilitating intramolecular chain transfer is not significantly affected and the molecular weights of polymers are in the same range as those obtained in bulk polymerization or polymerization in organic solvents.</description><subject>Applied sciences</subject><subject>branched polyethers</subject><subject>cationic polymerization</subject><subject>Exact sciences and technology</subject><subject>ionic liquid</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkDtPwzAUhS0EEqWwMmdhdLl-xc1YRVAqpYB4iNFy7EQ1pEmxi2j49aQNKmxM9_mdq3sQOicwIgD0cqm9GVEA1hUJP0ADIijBLKHysMuBUkwYi4_RSQivADDmQAcoS_XaNbUz0X1TtcvCu69dI2rKiOGr9aKtMMOL1vpm0423dbMp1rouIldHuo5mOzhz7x_OnqKjUlehOPuJQ_R8ffWU3uDsbjpLJxk2TAiOc8mlTjhnnIEd5zG3nJBY2rw0QEoTW27GCbGWSIhFQrsUDNFGEktZLjRnQzTqdY1vQvBFqVbede-3ioDaeqG2Xqi9Fx1w0QMrHYyuSq9r48IvJSQVnEC3l_R7n64q2n9U1XzykP69gXvWhXWx2bPav6lYMinUy-1UsSkj8ZxK9ci-AQ2JfmU</recordid><startdate>200404</startdate><enddate>200404</enddate><creator>Biedroń, Tadeusz</creator><creator>Bednarek, Melania</creator><creator>Kubisa, Przemysław</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200404</creationdate><title>Cationic Polymerization of 3-Ethyl-3-hydroxymethyloxetane in an Ionic Liquid</title><author>Biedroń, Tadeusz ; Bednarek, Melania ; Kubisa, Przemysław</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3554-b747a9443430d8b64d41167dbfc01fc6d4c891dd170659291d0c1ac71d23b5a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>branched polyethers</topic><topic>cationic polymerization</topic><topic>Exact sciences and technology</topic><topic>ionic liquid</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Bednarek, Melania</creatorcontrib><creatorcontrib>Kubisa, Przemysław</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biedroń, Tadeusz</au><au>Bednarek, Melania</au><au>Kubisa, Przemysław</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cationic Polymerization of 3-Ethyl-3-hydroxymethyloxetane in an Ionic Liquid</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2004-04</date><risdate>2004</risdate><volume>25</volume><issue>8</issue><spage>878</spage><epage>881</epage><pages>878-881</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>Cationic ring‐opening polymerization of 3‐ethyl‐3‐hydroxymethyloxetane (EOX) in a neutral ionic liquid (1‐butyl‐3‐methylimidazolium tetrafluoroborate, [bmim][BF4]) leading to a multihydroxyl, branched polyether proceeds readily to nearly quantitative conversion. Because of the relatively high polarity of ionic liquids, intermolecular hydrogen bonding leading to the formation of aggregates is reduced considerably. On the other hand, intramolecular hydrogen bonding facilitating intramolecular chain transfer is not significantly affected and the molecular weights of polymers are in the same range as those obtained in bulk polymerization or polymerization in organic solvents.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200300294</doi><tpages>4</tpages></addata></record> |
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| subjects | Applied sciences branched polyethers cationic polymerization Exact sciences and technology ionic liquid Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Cationic Polymerization of 3-Ethyl-3-hydroxymethyloxetane in an Ionic Liquid |
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