Double Yielding in a Styrene/Butadiene Star Block Copolymer
The morphology and tensile deformation behaviour of a highly asymmetric styrene/butadiene star block copolymer (polystyrene (PS) content = 74%) containing random PS‐co‐PB (polybutadiene) copolymer as a rubbery phase were investigated. The existence of double yielding, similar to that observed in som...
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Veröffentlicht in: | Macromolecular rapid communications. 2004-03, Vol.25 (5), p.653-658 |
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creator | Adhikari, Rameshwar Buschnakowski, Matthias Henning, Sven Goerlitz, Sylvia Huy, Trinh An Lebek, Werner Godehardt, Reinhold Michler, Georg Hannes Lach, Ralf Geiger, Kalman Knoll, Konrad |
description | The morphology and tensile deformation behaviour of a highly asymmetric styrene/butadiene star block copolymer (polystyrene (PS) content = 74%) containing random PS‐co‐PB (polybutadiene) copolymer as a rubbery phase were investigated. The existence of double yielding, similar to that observed in some semicrystalline polymers, was detected in this nanostructured amorphous polymer. The observed phenomenon may be correlated with two different micromechanical processes taking place at the initial stage of deformation.
The stress‐strain curve of the star block copolymer prepared here (each curve represents a different method). The two yield points are clearly visible (labelled I and II). |
doi_str_mv | 10.1002/marc.200300186 |
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The stress‐strain curve of the star block copolymer prepared here (each curve represents a different method). The two yield points are clearly visible (labelled I and II).</description><subject>Applied sciences</subject><subject>deformation behaviour</subject><subject>double yielding</subject><subject>Exact sciences and technology</subject><subject>Mechanical properties</subject><subject>morphology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>styrene/butadiene star block copolymer</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFjz1PwzAQhi0EEqWwMmdhTHu2a8cWUxuggFpAfAjBYjmOg0xDUtmtIP-eVEGFjelend7nTg9CxxgGGIAMP7Q3AwJAAbDgO6iHGcExlSTZbTMQEmNK-T46COEdAMQISA-dntXrrLTRi7Nl7qq3yFWRjh5WjbeVHU7WK527NrUb7aNJWZtFlNbLumw-rD9Ee4Uugz36mX30dHH-mF7Gs9vpVTqexYYyxmOBTQ5CcIJtwg2n0lggQieUaG1zCVhrKAxLeJFRIjORjHIjCEibAcZSatpHg-6u8XUI3hZq6V1r2ygMaqOuNupqq94CJx2w1MHosvC6Mi78UoyNGMVJ25Nd79OVtvnnqpqP79O_P-KOdWFlv7as9gvFE5ow9XwzVZhcp3fzV6Ik_Qasu3gK</recordid><startdate>200403</startdate><enddate>200403</enddate><creator>Adhikari, Rameshwar</creator><creator>Buschnakowski, Matthias</creator><creator>Henning, Sven</creator><creator>Goerlitz, Sylvia</creator><creator>Huy, Trinh An</creator><creator>Lebek, Werner</creator><creator>Godehardt, Reinhold</creator><creator>Michler, Georg Hannes</creator><creator>Lach, Ralf</creator><creator>Geiger, Kalman</creator><creator>Knoll, Konrad</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200403</creationdate><title>Double Yielding in a Styrene/Butadiene Star Block Copolymer</title><author>Adhikari, Rameshwar ; Buschnakowski, Matthias ; Henning, Sven ; Goerlitz, Sylvia ; Huy, Trinh An ; Lebek, Werner ; Godehardt, Reinhold ; Michler, Georg Hannes ; Lach, Ralf ; Geiger, Kalman ; Knoll, Konrad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3556-81cd088621e76c639ce028a732aaed901aa0fc576fb329b874dc8209eb01199a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>deformation behaviour</topic><topic>double yielding</topic><topic>Exact sciences and technology</topic><topic>Mechanical properties</topic><topic>morphology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>styrene/butadiene star block copolymer</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adhikari, Rameshwar</creatorcontrib><creatorcontrib>Buschnakowski, Matthias</creatorcontrib><creatorcontrib>Henning, Sven</creatorcontrib><creatorcontrib>Goerlitz, Sylvia</creatorcontrib><creatorcontrib>Huy, Trinh An</creatorcontrib><creatorcontrib>Lebek, Werner</creatorcontrib><creatorcontrib>Godehardt, Reinhold</creatorcontrib><creatorcontrib>Michler, Georg Hannes</creatorcontrib><creatorcontrib>Lach, Ralf</creatorcontrib><creatorcontrib>Geiger, Kalman</creatorcontrib><creatorcontrib>Knoll, Konrad</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adhikari, Rameshwar</au><au>Buschnakowski, Matthias</au><au>Henning, Sven</au><au>Goerlitz, Sylvia</au><au>Huy, Trinh An</au><au>Lebek, Werner</au><au>Godehardt, Reinhold</au><au>Michler, Georg Hannes</au><au>Lach, Ralf</au><au>Geiger, Kalman</au><au>Knoll, Konrad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Double Yielding in a Styrene/Butadiene Star Block Copolymer</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2004-03</date><risdate>2004</risdate><volume>25</volume><issue>5</issue><spage>653</spage><epage>658</epage><pages>653-658</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The morphology and tensile deformation behaviour of a highly asymmetric styrene/butadiene star block copolymer (polystyrene (PS) content = 74%) containing random PS‐co‐PB (polybutadiene) copolymer as a rubbery phase were investigated. The existence of double yielding, similar to that observed in some semicrystalline polymers, was detected in this nanostructured amorphous polymer. The observed phenomenon may be correlated with two different micromechanical processes taking place at the initial stage of deformation.
The stress‐strain curve of the star block copolymer prepared here (each curve represents a different method). The two yield points are clearly visible (labelled I and II).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200300186</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences deformation behaviour double yielding Exact sciences and technology Mechanical properties morphology Organic polymers Physicochemistry of polymers Properties and characterization styrene/butadiene star block copolymer |
title | Double Yielding in a Styrene/Butadiene Star Block Copolymer |
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