Double Yielding in a Styrene/Butadiene Star Block Copolymer

The morphology and tensile deformation behaviour of a highly asymmetric styrene/butadiene star block copolymer (polystyrene (PS) content = 74%) containing random PS‐co‐PB (polybutadiene) copolymer as a rubbery phase were investigated. The existence of double yielding, similar to that observed in som...

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Veröffentlicht in:Macromolecular rapid communications. 2004-03, Vol.25 (5), p.653-658
Hauptverfasser: Adhikari, Rameshwar, Buschnakowski, Matthias, Henning, Sven, Goerlitz, Sylvia, Huy, Trinh An, Lebek, Werner, Godehardt, Reinhold, Michler, Georg Hannes, Lach, Ralf, Geiger, Kalman, Knoll, Konrad
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container_issue 5
container_start_page 653
container_title Macromolecular rapid communications.
container_volume 25
creator Adhikari, Rameshwar
Buschnakowski, Matthias
Henning, Sven
Goerlitz, Sylvia
Huy, Trinh An
Lebek, Werner
Godehardt, Reinhold
Michler, Georg Hannes
Lach, Ralf
Geiger, Kalman
Knoll, Konrad
description The morphology and tensile deformation behaviour of a highly asymmetric styrene/butadiene star block copolymer (polystyrene (PS) content = 74%) containing random PS‐co‐PB (polybutadiene) copolymer as a rubbery phase were investigated. The existence of double yielding, similar to that observed in some semicrystalline polymers, was detected in this nanostructured amorphous polymer. The observed phenomenon may be correlated with two different micromechanical processes taking place at the initial stage of deformation. The stress‐strain curve of the star block copolymer prepared here (each curve represents a different method). The two yield points are clearly visible (labelled I and II).
doi_str_mv 10.1002/marc.200300186
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subjects Applied sciences
deformation behaviour
double yielding
Exact sciences and technology
Mechanical properties
morphology
Organic polymers
Physicochemistry of polymers
Properties and characterization
styrene/butadiene star block copolymer
title Double Yielding in a Styrene/Butadiene Star Block Copolymer
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