Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization
Atom transfer radical polymerization (ATRP) is a robust method for the preparation of well‐defined (co)polymers. This process has also enabled the preparation of a wide range of polymer brushes where (co)polymers are covalently attached to either curved or flat surfaces. In this review, the general...
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| Veröffentlicht in: | Macromolecular rapid communications. 2003-12, Vol.24 (18), p.1043-1059 |
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| container_title | Macromolecular rapid communications. |
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| creator | Pyun, Jeffrey Kowalewski, Tomasz Matyjaszewski, Krzysztof |
| description | Atom transfer radical polymerization (ATRP) is a robust method for the preparation of well‐defined (co)polymers. This process has also enabled the preparation of a wide range of polymer brushes where (co)polymers are covalently attached to either curved or flat surfaces. In this review, the general methodology for the synthesis of polymer brushes from flat surfaces, polymers and colloids is summarized focusing on reports using ATRP. Additionally, the morphology of ultrathin films from polymer brushes is discussed using atomic force microscopy (AFM) and other techniques to confirm the formation of nanoscale structure and organization.
Formation of polymer brushes by ATRP. |
| doi_str_mv | 10.1002/marc.200300078 |
| format | Article |
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Formation of polymer brushes by ATRP.</description><subject>Applied sciences</subject><subject>atom transfer radical polymerization (ATRP)</subject><subject>atomic force microscopy (AFM)</subject><subject>Exact sciences and technology</subject><subject>interfaces</subject><subject>nanocomposites</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polymer brushes</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhi0EEqWwMmdhTLHPceyOpYIGqRRUWjFajuuAIU0qOxWEX4-rQGFjutPd-9zHi9A5wQOCMVyuldMDwJhijLk4QD3CgMR0CPww5BggJpSmx-jE-9cgEQmGHpo8tlXzYrz1UV1ED3XZro2LrtzWh2K09LZ6jkZNvY4WTlW-CL25Wlmtyh-t_VSNratTdFSo0puz79hHy5vrxTiLp_eT2_FoGusEiIgFYZoxo6haYWAaDMmLgoLOQWHNjdKCcJzkq5xyA1zkIBKSqBRyY0BTktM-GnRztau9d6aQG2fD560kWO5skDsb5N6GAFx0wEb5cHYR3tDW_1KMihQEBN2w073b0rT_TJV3o_n47464Y61vzMeeVe5NppxyJp9mE5nNsixlhEhGvwBxln34</recordid><startdate>200312</startdate><enddate>200312</enddate><creator>Pyun, Jeffrey</creator><creator>Kowalewski, Tomasz</creator><creator>Matyjaszewski, Krzysztof</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200312</creationdate><title>Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization</title><author>Pyun, Jeffrey ; Kowalewski, Tomasz ; Matyjaszewski, Krzysztof</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4218-815c55ea3ad025c2e1bff32cb2a0c7eac81704bdb37e278b28414a62bee2c31b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>atom transfer radical polymerization (ATRP)</topic><topic>atomic force microscopy (AFM)</topic><topic>Exact sciences and technology</topic><topic>interfaces</topic><topic>nanocomposites</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polymer brushes</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pyun, Jeffrey</creatorcontrib><creatorcontrib>Kowalewski, Tomasz</creatorcontrib><creatorcontrib>Matyjaszewski, Krzysztof</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pyun, Jeffrey</au><au>Kowalewski, Tomasz</au><au>Matyjaszewski, Krzysztof</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2003-12</date><risdate>2003</risdate><volume>24</volume><issue>18</issue><spage>1043</spage><epage>1059</epage><pages>1043-1059</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>Atom transfer radical polymerization (ATRP) is a robust method for the preparation of well‐defined (co)polymers. This process has also enabled the preparation of a wide range of polymer brushes where (co)polymers are covalently attached to either curved or flat surfaces. In this review, the general methodology for the synthesis of polymer brushes from flat surfaces, polymers and colloids is summarized focusing on reports using ATRP. Additionally, the morphology of ultrathin films from polymer brushes is discussed using atomic force microscopy (AFM) and other techniques to confirm the formation of nanoscale structure and organization.
Formation of polymer brushes by ATRP.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200300078</doi><tpages>17</tpages></addata></record> |
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| ispartof | Macromolecular rapid communications., 2003-12, Vol.24 (18), p.1043-1059 |
| issn | 1022-1336 1521-3927 |
| language | eng |
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| source | Wiley Journals |
| subjects | Applied sciences atom transfer radical polymerization (ATRP) atomic force microscopy (AFM) Exact sciences and technology interfaces nanocomposites Organic polymers Physicochemistry of polymers polymer brushes Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization |
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