Association thickener by host guest interaction of a β-cyclodextrin polymer and a polymer with hydrophobic side-groups

A host polymer with pending β‐cyclodextrin side‐groups and a guest polymer with pending hydrophobic 4‐tert‐butylanilide side groups were synthesized by polymeranalogous reactions starting from poly[(maleic anhydride)‐alt‐(isobutene)] (M̄w = 60000). The inclusions of both polymers with complementary...

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Veröffentlicht in:Macromolecular rapid communications. 1997-12, Vol.18 (12), p.1117-1123
Hauptverfasser: Weickenmeier, Meik, Wenz, Gerhard, Huff, Jürgen
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container_title Macromolecular rapid communications.
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creator Weickenmeier, Meik
Wenz, Gerhard
Huff, Jürgen
description A host polymer with pending β‐cyclodextrin side‐groups and a guest polymer with pending hydrophobic 4‐tert‐butylanilide side groups were synthesized by polymeranalogous reactions starting from poly[(maleic anhydride)‐alt‐(isobutene)] (M̄w = 60000). The inclusions of both polymers with complementary monomeric guests and hosts are proven by microcalorimetry. The interaction of the host polymer and the guest polymer in aqueous solution is accompanied by a tremendous increase in viscosity.
doi_str_mv 10.1002/marc.1997.030181216
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subjects Applied sciences
Chemical modifications
Chemical reactions and properties
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
title Association thickener by host guest interaction of a β-cyclodextrin polymer and a polymer with hydrophobic side-groups
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