Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven
The formation of an integral asymmetric membrane composed of a cylinder‐forming polystyrene‐block‐poly(2‐vinylpyridine) on a nonwoven by using solvent casting followed by solvent/nonsolvent exchange (phase inversion) is reported for the first time. The influence of parameters such as solvent composi...
Gespeichert in:
| Veröffentlicht in: | Macromolecular materials and engineering 2012-08, Vol.297 (8), p.790-798 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 798 |
|---|---|
| container_issue | 8 |
| container_start_page | 790 |
| container_title | Macromolecular materials and engineering |
| container_volume | 297 |
| creator | Jung, Adina Rangou, Sofia Abetz, Clarissa Filiz, Volkan Abetz, Volker |
| description | The formation of an integral asymmetric membrane composed of a cylinder‐forming polystyrene‐block‐poly(2‐vinylpyridine) on a nonwoven by using solvent casting followed by solvent/nonsolvent exchange (phase inversion) is reported for the first time. The influence of parameters such as solvent composition, evaporation time of the solution‐cast block copolymer film before phase inversion, and immersion bath temperature is demonstrated. The optimized membranes are characterized in terms of stimuli‐responsive water flux properties. The morphologies of the membranes as well as of the bulk of the block copolymer are imaged by scanning force microscopy, scanning electron microscopy, and transmission electron microscopy.
Integral asymmetric composite membranes with a PS‐b‐P2VP top layer are shown for the first time. The quality of the membrane structure is discussed in terms of solvent composition, evaporation time of the cast block copolymer solution on a nonwoven before immersion, and temperature of the immersion bath. The stimuli‐responsive membranes are characterized by pH‐dependent water flux measurements. |
| doi_str_mv | 10.1002/mame.201100359 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_mame_201100359</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>MAME201100359</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3579-6dec16c8be876f4f4d3c8ca2f2ce3ab3e202a1b209b1de1ac6a5bea3e28e78e23</originalsourceid><addsrcrecordid>eNqFkEtPwkAUhRujiYhuXXdjoovBefQ1S0LkoYBENC4n0-HWjLQdMlPA_ntbMcSdq_vI-c7NPZ53TXCPYEzvC1lAj2LSDCzkJ16HBIwjisPg9KdPUBxweu5dOPeJMYkTzjreflnZraq2FvyhsYWstCl9k_mTsoIPK3O_7-qigMpq5Q9MsTFOV-DPoEitLMG10oXJa1fVFkpAaW7UGrWbW4p2uqzzTW31Spdw5zfG0p-bcm92UF56Z5nMHVz91q73Nnx4HYzR9Hk0GfSnSLEw5ihagSKRSlJI4igLsmDFVKIkzagCJlMGFFNJUop5SlZApIpkmIJs9gnECVDW9XoHX2WNcxYysbG6kLYWBIs2NtHGJo6xNcDNAdhIp2SeNW8q7Y4UjShjnMWNjh90e51D_Y-rmPVnD39voAOrXQVfR1batYhiFofifT4S_PFpvFjiULywb-AZkVE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Jung, Adina ; Rangou, Sofia ; Abetz, Clarissa ; Filiz, Volkan ; Abetz, Volker</creator><creatorcontrib>Jung, Adina ; Rangou, Sofia ; Abetz, Clarissa ; Filiz, Volkan ; Abetz, Volker</creatorcontrib><description>The formation of an integral asymmetric membrane composed of a cylinder‐forming polystyrene‐block‐poly(2‐vinylpyridine) on a nonwoven by using solvent casting followed by solvent/nonsolvent exchange (phase inversion) is reported for the first time. The influence of parameters such as solvent composition, evaporation time of the solution‐cast block copolymer film before phase inversion, and immersion bath temperature is demonstrated. The optimized membranes are characterized in terms of stimuli‐responsive water flux properties. The morphologies of the membranes as well as of the bulk of the block copolymer are imaged by scanning force microscopy, scanning electron microscopy, and transmission electron microscopy.
Integral asymmetric composite membranes with a PS‐b‐P2VP top layer are shown for the first time. The quality of the membrane structure is discussed in terms of solvent composition, evaporation time of the cast block copolymer solution on a nonwoven before immersion, and temperature of the immersion bath. The stimuli‐responsive membranes are characterized by pH‐dependent water flux measurements.</description><identifier>ISSN: 1438-7492</identifier><identifier>EISSN: 1439-2054</identifier><identifier>DOI: 10.1002/mame.201100359</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; Exact sciences and technology ; Exchange resins and membranes ; Forms of application and semi-finished materials ; membranes ; phase separation ; Polymer industry, paints, wood ; self-assembly ; stimuli-sensitive polymers ; Technology of polymers</subject><ispartof>Macromolecular materials and engineering, 2012-08, Vol.297 (8), p.790-798</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3579-6dec16c8be876f4f4d3c8ca2f2ce3ab3e202a1b209b1de1ac6a5bea3e28e78e23</citedby><cites>FETCH-LOGICAL-c3579-6dec16c8be876f4f4d3c8ca2f2ce3ab3e202a1b209b1de1ac6a5bea3e28e78e23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmame.201100359$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmame.201100359$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26233937$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jung, Adina</creatorcontrib><creatorcontrib>Rangou, Sofia</creatorcontrib><creatorcontrib>Abetz, Clarissa</creatorcontrib><creatorcontrib>Filiz, Volkan</creatorcontrib><creatorcontrib>Abetz, Volker</creatorcontrib><title>Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven</title><title>Macromolecular materials and engineering</title><addtitle>Macromol. Mater. Eng</addtitle><description>The formation of an integral asymmetric membrane composed of a cylinder‐forming polystyrene‐block‐poly(2‐vinylpyridine) on a nonwoven by using solvent casting followed by solvent/nonsolvent exchange (phase inversion) is reported for the first time. The influence of parameters such as solvent composition, evaporation time of the solution‐cast block copolymer film before phase inversion, and immersion bath temperature is demonstrated. The optimized membranes are characterized in terms of stimuli‐responsive water flux properties. The morphologies of the membranes as well as of the bulk of the block copolymer are imaged by scanning force microscopy, scanning electron microscopy, and transmission electron microscopy.
Integral asymmetric composite membranes with a PS‐b‐P2VP top layer are shown for the first time. The quality of the membrane structure is discussed in terms of solvent composition, evaporation time of the cast block copolymer solution on a nonwoven before immersion, and temperature of the immersion bath. The stimuli‐responsive membranes are characterized by pH‐dependent water flux measurements.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Forms of application and semi-finished materials</subject><subject>membranes</subject><subject>phase separation</subject><subject>Polymer industry, paints, wood</subject><subject>self-assembly</subject><subject>stimuli-sensitive polymers</subject><subject>Technology of polymers</subject><issn>1438-7492</issn><issn>1439-2054</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwkAUhRujiYhuXXdjoovBefQ1S0LkoYBENC4n0-HWjLQdMlPA_ntbMcSdq_vI-c7NPZ53TXCPYEzvC1lAj2LSDCzkJ16HBIwjisPg9KdPUBxweu5dOPeJMYkTzjreflnZraq2FvyhsYWstCl9k_mTsoIPK3O_7-qigMpq5Q9MsTFOV-DPoEitLMG10oXJa1fVFkpAaW7UGrWbW4p2uqzzTW31Spdw5zfG0p-bcm92UF56Z5nMHVz91q73Nnx4HYzR9Hk0GfSnSLEw5ihagSKRSlJI4igLsmDFVKIkzagCJlMGFFNJUop5SlZApIpkmIJs9gnECVDW9XoHX2WNcxYysbG6kLYWBIs2NtHGJo6xNcDNAdhIp2SeNW8q7Y4UjShjnMWNjh90e51D_Y-rmPVnD39voAOrXQVfR1batYhiFofifT4S_PFpvFjiULywb-AZkVE</recordid><startdate>201208</startdate><enddate>201208</enddate><creator>Jung, Adina</creator><creator>Rangou, Sofia</creator><creator>Abetz, Clarissa</creator><creator>Filiz, Volkan</creator><creator>Abetz, Volker</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201208</creationdate><title>Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven</title><author>Jung, Adina ; Rangou, Sofia ; Abetz, Clarissa ; Filiz, Volkan ; Abetz, Volker</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3579-6dec16c8be876f4f4d3c8ca2f2ce3ab3e202a1b209b1de1ac6a5bea3e28e78e23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Forms of application and semi-finished materials</topic><topic>membranes</topic><topic>phase separation</topic><topic>Polymer industry, paints, wood</topic><topic>self-assembly</topic><topic>stimuli-sensitive polymers</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jung, Adina</creatorcontrib><creatorcontrib>Rangou, Sofia</creatorcontrib><creatorcontrib>Abetz, Clarissa</creatorcontrib><creatorcontrib>Filiz, Volkan</creatorcontrib><creatorcontrib>Abetz, Volker</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular materials and engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jung, Adina</au><au>Rangou, Sofia</au><au>Abetz, Clarissa</au><au>Filiz, Volkan</au><au>Abetz, Volker</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven</atitle><jtitle>Macromolecular materials and engineering</jtitle><addtitle>Macromol. Mater. Eng</addtitle><date>2012-08</date><risdate>2012</risdate><volume>297</volume><issue>8</issue><spage>790</spage><epage>798</epage><pages>790-798</pages><issn>1438-7492</issn><eissn>1439-2054</eissn><abstract>The formation of an integral asymmetric membrane composed of a cylinder‐forming polystyrene‐block‐poly(2‐vinylpyridine) on a nonwoven by using solvent casting followed by solvent/nonsolvent exchange (phase inversion) is reported for the first time. The influence of parameters such as solvent composition, evaporation time of the solution‐cast block copolymer film before phase inversion, and immersion bath temperature is demonstrated. The optimized membranes are characterized in terms of stimuli‐responsive water flux properties. The morphologies of the membranes as well as of the bulk of the block copolymer are imaged by scanning force microscopy, scanning electron microscopy, and transmission electron microscopy.
Integral asymmetric composite membranes with a PS‐b‐P2VP top layer are shown for the first time. The quality of the membrane structure is discussed in terms of solvent composition, evaporation time of the cast block copolymer solution on a nonwoven before immersion, and temperature of the immersion bath. The stimuli‐responsive membranes are characterized by pH‐dependent water flux measurements.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/mame.201100359</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1438-7492 |
| ispartof | Macromolecular materials and engineering, 2012-08, Vol.297 (8), p.790-798 |
| issn | 1438-7492 1439-2054 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_mame_201100359 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials membranes phase separation Polymer industry, paints, wood self-assembly stimuli-sensitive polymers Technology of polymers |
| title | Structure Formation of Integral Asymmetric Composite Membranes of Polystyrene-block-Poly(2-vinylpyridine) on a Nonwoven |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-03T20%3A26%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Structure%20Formation%20of%20Integral%20Asymmetric%20Composite%20Membranes%20of%20Polystyrene-block-Poly(2-vinylpyridine)%20on%20a%20Nonwoven&rft.jtitle=Macromolecular%20materials%20and%20engineering&rft.au=Jung,%20Adina&rft.date=2012-08&rft.volume=297&rft.issue=8&rft.spage=790&rft.epage=798&rft.pages=790-798&rft.issn=1438-7492&rft.eissn=1439-2054&rft_id=info:doi/10.1002/mame.201100359&rft_dat=%3Cwiley_cross%3EMAME201100359%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |