Synthesis and Photovoltaic Properties of a Poly(2,7-carbazole) Derivative Based on Dithienosilole and Benzothiadiazole
A low bandgap poly(2,7‐carbazole) derivative PCDSBT containing dithienosilole and benzothiadiazole is synthesized by Stille polymerization. The incorporation of dithienosilole and carbazole causes PCDSBT to have a broad absorption from 350 to 800 nm and a relatively low HOMO level. Solar cell device...
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| Veröffentlicht in: | Macromolecular chemistry and physics 2011-06, Vol.212 (11), p.1109-1114 |
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| creator | Zhou, Jiaoyan Wan, Xiangjian Liu, Yongsheng Wang, Fei Long, Guankui Li, Chenxi Chen, Yongsheng |
| description | A low bandgap poly(2,7‐carbazole) derivative PCDSBT containing dithienosilole and benzothiadiazole is synthesized by Stille polymerization. The incorporation of dithienosilole and carbazole causes PCDSBT to have a broad absorption from 350 to 800 nm and a relatively low HOMO level. Solar cell devices fabricated by blending PCDSBT with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM) at a 1:2 weight ratio in a mixed solvent of 3% (by volume), 1,8‐diiodooctane, and 97% dichlorobenzene lead to a power conversion efficiency of 1.65% under the illumination of AM 1.5G (100 mW · cm−2).
A poly(2,7‐carbazole) derivative PCDSBT with dithienosilole and benzothiadiazole is designed and synthesized. PCDSBT has a narrow bandgap and a relatively low HOMO level. A power conversion efficiency of 1.65% is achieved for this polymer when 1,8‐diiodooctane is used as an additive. |
| doi_str_mv | 10.1002/macp.201100060 |
| format | Article |
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A poly(2,7‐carbazole) derivative PCDSBT with dithienosilole and benzothiadiazole is designed and synthesized. PCDSBT has a narrow bandgap and a relatively low HOMO level. A power conversion efficiency of 1.65% is achieved for this polymer when 1,8‐diiodooctane is used as an additive.</description><identifier>ISSN: 1022-1352</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.201100060</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; carbazole ; dithienosilole ; Energy ; Exact sciences and technology ; Natural energy ; Organic polymers ; photochemistry ; Photovoltaic conversion ; Physicochemistry of polymers ; polymer bulk heterojunction solar cells ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Solar cells. Photoelectrochemical cells ; Solar energy</subject><ispartof>Macromolecular chemistry and physics, 2011-06, Vol.212 (11), p.1109-1114</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4230-88044e5262d1defb3494ca34c97ce18d467ca6a731d47c41a362d5cab1059173</citedby><cites>FETCH-LOGICAL-c4230-88044e5262d1defb3494ca34c97ce18d467ca6a731d47c41a362d5cab1059173</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.201100060$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.201100060$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24520704$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhou, Jiaoyan</creatorcontrib><creatorcontrib>Wan, Xiangjian</creatorcontrib><creatorcontrib>Liu, Yongsheng</creatorcontrib><creatorcontrib>Wang, Fei</creatorcontrib><creatorcontrib>Long, Guankui</creatorcontrib><creatorcontrib>Li, Chenxi</creatorcontrib><creatorcontrib>Chen, Yongsheng</creatorcontrib><title>Synthesis and Photovoltaic Properties of a Poly(2,7-carbazole) Derivative Based on Dithienosilole and Benzothiadiazole</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>A low bandgap poly(2,7‐carbazole) derivative PCDSBT containing dithienosilole and benzothiadiazole is synthesized by Stille polymerization. The incorporation of dithienosilole and carbazole causes PCDSBT to have a broad absorption from 350 to 800 nm and a relatively low HOMO level. Solar cell devices fabricated by blending PCDSBT with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM) at a 1:2 weight ratio in a mixed solvent of 3% (by volume), 1,8‐diiodooctane, and 97% dichlorobenzene lead to a power conversion efficiency of 1.65% under the illumination of AM 1.5G (100 mW · cm−2).
A poly(2,7‐carbazole) derivative PCDSBT with dithienosilole and benzothiadiazole is designed and synthesized. PCDSBT has a narrow bandgap and a relatively low HOMO level. A power conversion efficiency of 1.65% is achieved for this polymer when 1,8‐diiodooctane is used as an additive.</description><subject>Applied sciences</subject><subject>carbazole</subject><subject>dithienosilole</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Organic polymers</subject><subject>photochemistry</subject><subject>Photovoltaic conversion</subject><subject>Physicochemistry of polymers</subject><subject>polymer bulk heterojunction solar cells</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkF1LwzAUhosoOKe3XudGULAzX23Wy33olE0tOJh34SxNWbRrSlKm26-322R459XJCc_zHniD4JLgDsGY3i1BVR2KSbPgGB8FLRJRErKERcfNG1MaEhbR0-DM-48G6eJEtILV27qsF9obj6DMULqwtV3ZogajUOpspV1ttEc2R4BSW6yv6a0IFbg5bGyhb9BQO7OC2qw06oPXGbIlGpp6YXRpvSkaZpfb1-XGNr-QmZ14HpzkUHh98TvbwfThfjp4DCevo6dBbxIqThkOu13MuY5oTDOS6XzOeMIVMK4SoTTpZjwWCmIQjGRcKE6ANWSkYE5wlBDB2kFnH6uc9d7pXFbOLMGtJcFyW5rcliYPpTXC1V6owCsocgelMv5gUR5RLDBvuGTPfZlCr_9Jlc-9Qfr3Rrh3ja_198EF9yljwUQkZy8jOY7pbDym73LIfgBw1428</recordid><startdate>20110601</startdate><enddate>20110601</enddate><creator>Zhou, Jiaoyan</creator><creator>Wan, Xiangjian</creator><creator>Liu, Yongsheng</creator><creator>Wang, Fei</creator><creator>Long, Guankui</creator><creator>Li, Chenxi</creator><creator>Chen, Yongsheng</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110601</creationdate><title>Synthesis and Photovoltaic Properties of a Poly(2,7-carbazole) Derivative Based on Dithienosilole and Benzothiadiazole</title><author>Zhou, Jiaoyan ; Wan, Xiangjian ; Liu, Yongsheng ; Wang, Fei ; Long, Guankui ; Li, Chenxi ; Chen, Yongsheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4230-88044e5262d1defb3494ca34c97ce18d467ca6a731d47c41a362d5cab1059173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>carbazole</topic><topic>dithienosilole</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Natural energy</topic><topic>Organic polymers</topic><topic>photochemistry</topic><topic>Photovoltaic conversion</topic><topic>Physicochemistry of polymers</topic><topic>polymer bulk heterojunction solar cells</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Jiaoyan</creatorcontrib><creatorcontrib>Wan, Xiangjian</creatorcontrib><creatorcontrib>Liu, Yongsheng</creatorcontrib><creatorcontrib>Wang, Fei</creatorcontrib><creatorcontrib>Long, Guankui</creatorcontrib><creatorcontrib>Li, Chenxi</creatorcontrib><creatorcontrib>Chen, Yongsheng</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Jiaoyan</au><au>Wan, Xiangjian</au><au>Liu, Yongsheng</au><au>Wang, Fei</au><au>Long, Guankui</au><au>Li, Chenxi</au><au>Chen, Yongsheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Photovoltaic Properties of a Poly(2,7-carbazole) Derivative Based on Dithienosilole and Benzothiadiazole</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. Chem. Phys</addtitle><date>2011-06-01</date><risdate>2011</risdate><volume>212</volume><issue>11</issue><spage>1109</spage><epage>1114</epage><pages>1109-1114</pages><issn>1022-1352</issn><eissn>1521-3935</eissn><abstract>A low bandgap poly(2,7‐carbazole) derivative PCDSBT containing dithienosilole and benzothiadiazole is synthesized by Stille polymerization. The incorporation of dithienosilole and carbazole causes PCDSBT to have a broad absorption from 350 to 800 nm and a relatively low HOMO level. Solar cell devices fabricated by blending PCDSBT with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM) at a 1:2 weight ratio in a mixed solvent of 3% (by volume), 1,8‐diiodooctane, and 97% dichlorobenzene lead to a power conversion efficiency of 1.65% under the illumination of AM 1.5G (100 mW · cm−2).
A poly(2,7‐carbazole) derivative PCDSBT with dithienosilole and benzothiadiazole is designed and synthesized. PCDSBT has a narrow bandgap and a relatively low HOMO level. A power conversion efficiency of 1.65% is achieved for this polymer when 1,8‐diiodooctane is used as an additive.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/macp.201100060</doi><tpages>6</tpages></addata></record> |
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| source | Wiley-Blackwell Journals |
| subjects | Applied sciences carbazole dithienosilole Energy Exact sciences and technology Natural energy Organic polymers photochemistry Photovoltaic conversion Physicochemistry of polymers polymer bulk heterojunction solar cells Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solar cells. Photoelectrochemical cells Solar energy |
| title | Synthesis and Photovoltaic Properties of a Poly(2,7-carbazole) Derivative Based on Dithienosilole and Benzothiadiazole |
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