Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells
Novel readily soluble random low‐band‐gap conjugated copolymers (PFO–DTTP, Eg ≈ 1.77–2.00 eV) derived from 9,9‐dioctylfluorene (DOF) and 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine (DTTP) were prepared. The solutions and the solid thin films of the copolymers absorbed light from 300–690 nm....
Gespeichert in:
| Veröffentlicht in: | Macromolecular chemistry and physics 2006-03, Vol.207 (5), p.511-520 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 520 |
|---|---|
| container_issue | 5 |
| container_start_page | 511 |
| container_title | Macromolecular chemistry and physics |
| container_volume | 207 |
| creator | Xia, Yangjun Luo, Jie Deng, Xianyu Li, Xianzhen Li, Dongyun Zhu, Xuhui Yang, Wei Cao, Yong |
| description | Novel readily soluble random low‐band‐gap conjugated copolymers (PFO–DTTP, Eg ≈ 1.77–2.00 eV) derived from 9,9‐dioctylfluorene (DOF) and 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine (DTTP) were prepared. The solutions and the solid thin films of the copolymers absorbed light from 300–690 nm. Prototype photovoltaic cells from solid state composite films with the copolymer PFO–DTTP30 and [6,6]‐phenyl C61 butyric acid methyl ester (PCBM) showed power conversion efficiencies up to 0.83% under an AM1.5 solar simulator (100 mW · cm−2). For electroluminescent devices, the emission peaks were around 734–780 nm. This indicates that the low band gap copolymers are promising materials for polymeric solar cells and deep red/near infrared light‐emitting diodes.
Synthesis of novel low‐band‐gap fluorene‐based copolymer. |
| doi_str_mv | 10.1002/macp.200500517 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_macp_200500517</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>MACP200500517</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4237-bb22039c00463b0e2da939892aa690de4aa8238c33927b61e0107ac5f9bc9f503</originalsourceid><addsrcrecordid>eNqFkEFP3DAQhaOqSKWUa8--9JhlbK838ZENsIuUbhEC9Wg5zgQMThzZWWB_Rf9yjbaC3pBGmtHofW80L8u-U5hRAHbSazPOGIBIRYtP2SEVjOZccvE5zcBYTrlgX7KvMT4AQAmyOMz-bPwTOnKth9b3pPbP-TKN-UqP5MJtfcAB0yZiSyo_erfrMUTS-UDOEEdyje3JBnUgl0MXdEiq2t7dT_l5b6fJDnfkzPoWI0mWZLl1j2SNEwb_sB3MZP1Aru795J-8m7Q1pELn4rfsoNMu4vG_fpTdXpzfVOu8_rW6rE7r3MwZL_KmYQy4NADzBW8AWasll6VkWi8ktDjXumS8NJxLVjQLikCh0EZ0sjGyE8CPstne1wQfY8BOjcH2OuwUBfUap3qNU73FmYAfe2DU0WiX3h2Mje9UIUQhOEs6udc9W4e7D1zVz9Pq6v8b-Z61ccKXN1aHR7UoeCHU781KLSWta16uleR_AVNNlkA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells</title><source>Access via Wiley Online Library</source><creator>Xia, Yangjun ; Luo, Jie ; Deng, Xianyu ; Li, Xianzhen ; Li, Dongyun ; Zhu, Xuhui ; Yang, Wei ; Cao, Yong</creator><creatorcontrib>Xia, Yangjun ; Luo, Jie ; Deng, Xianyu ; Li, Xianzhen ; Li, Dongyun ; Zhu, Xuhui ; Yang, Wei ; Cao, Yong</creatorcontrib><description>Novel readily soluble random low‐band‐gap conjugated copolymers (PFO–DTTP, Eg ≈ 1.77–2.00 eV) derived from 9,9‐dioctylfluorene (DOF) and 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine (DTTP) were prepared. The solutions and the solid thin films of the copolymers absorbed light from 300–690 nm. Prototype photovoltaic cells from solid state composite films with the copolymer PFO–DTTP30 and [6,6]‐phenyl C61 butyric acid methyl ester (PCBM) showed power conversion efficiencies up to 0.83% under an AM1.5 solar simulator (100 mW · cm−2). For electroluminescent devices, the emission peaks were around 734–780 nm. This indicates that the low band gap copolymers are promising materials for polymeric solar cells and deep red/near infrared light‐emitting diodes.
Synthesis of novel low‐band‐gap fluorene‐based copolymer.</description><identifier>ISSN: 1022-1352</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.200500517</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine ; 3-dimethyl-5 ; 4-b]pyrazine ; 7-dithien-2-yl-thieno ; 9,9‐dioctylfluorene ; 9-dioctylfluorene ; Applied sciences ; conjugated polymers ; Electronics ; Exact sciences and technology ; light-emitting diodes (LED) ; Optoelectronic devices ; Organic polymers ; photovoltaic cells ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</subject><ispartof>Macromolecular chemistry and physics, 2006-03, Vol.207 (5), p.511-520</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4237-bb22039c00463b0e2da939892aa690de4aa8238c33927b61e0107ac5f9bc9f503</citedby><cites>FETCH-LOGICAL-c4237-bb22039c00463b0e2da939892aa690de4aa8238c33927b61e0107ac5f9bc9f503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.200500517$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.200500517$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17557532$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xia, Yangjun</creatorcontrib><creatorcontrib>Luo, Jie</creatorcontrib><creatorcontrib>Deng, Xianyu</creatorcontrib><creatorcontrib>Li, Xianzhen</creatorcontrib><creatorcontrib>Li, Dongyun</creatorcontrib><creatorcontrib>Zhu, Xuhui</creatorcontrib><creatorcontrib>Yang, Wei</creatorcontrib><creatorcontrib>Cao, Yong</creatorcontrib><title>Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>Novel readily soluble random low‐band‐gap conjugated copolymers (PFO–DTTP, Eg ≈ 1.77–2.00 eV) derived from 9,9‐dioctylfluorene (DOF) and 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine (DTTP) were prepared. The solutions and the solid thin films of the copolymers absorbed light from 300–690 nm. Prototype photovoltaic cells from solid state composite films with the copolymer PFO–DTTP30 and [6,6]‐phenyl C61 butyric acid methyl ester (PCBM) showed power conversion efficiencies up to 0.83% under an AM1.5 solar simulator (100 mW · cm−2). For electroluminescent devices, the emission peaks were around 734–780 nm. This indicates that the low band gap copolymers are promising materials for polymeric solar cells and deep red/near infrared light‐emitting diodes.
Synthesis of novel low‐band‐gap fluorene‐based copolymer.</description><subject>2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine</subject><subject>3-dimethyl-5</subject><subject>4-b]pyrazine</subject><subject>7-dithien-2-yl-thieno</subject><subject>9,9‐dioctylfluorene</subject><subject>9-dioctylfluorene</subject><subject>Applied sciences</subject><subject>conjugated polymers</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>light-emitting diodes (LED)</subject><subject>Optoelectronic devices</subject><subject>Organic polymers</subject><subject>photovoltaic cells</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkEFP3DAQhaOqSKWUa8--9JhlbK838ZENsIuUbhEC9Wg5zgQMThzZWWB_Rf9yjbaC3pBGmtHofW80L8u-U5hRAHbSazPOGIBIRYtP2SEVjOZccvE5zcBYTrlgX7KvMT4AQAmyOMz-bPwTOnKth9b3pPbP-TKN-UqP5MJtfcAB0yZiSyo_erfrMUTS-UDOEEdyje3JBnUgl0MXdEiq2t7dT_l5b6fJDnfkzPoWI0mWZLl1j2SNEwb_sB3MZP1Aru795J-8m7Q1pELn4rfsoNMu4vG_fpTdXpzfVOu8_rW6rE7r3MwZL_KmYQy4NADzBW8AWasll6VkWi8ktDjXumS8NJxLVjQLikCh0EZ0sjGyE8CPstne1wQfY8BOjcH2OuwUBfUap3qNU73FmYAfe2DU0WiX3h2Mje9UIUQhOEs6udc9W4e7D1zVz9Pq6v8b-Z61ccKXN1aHR7UoeCHU781KLSWta16uleR_AVNNlkA</recordid><startdate>20060303</startdate><enddate>20060303</enddate><creator>Xia, Yangjun</creator><creator>Luo, Jie</creator><creator>Deng, Xianyu</creator><creator>Li, Xianzhen</creator><creator>Li, Dongyun</creator><creator>Zhu, Xuhui</creator><creator>Yang, Wei</creator><creator>Cao, Yong</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060303</creationdate><title>Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells</title><author>Xia, Yangjun ; Luo, Jie ; Deng, Xianyu ; Li, Xianzhen ; Li, Dongyun ; Zhu, Xuhui ; Yang, Wei ; Cao, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4237-bb22039c00463b0e2da939892aa690de4aa8238c33927b61e0107ac5f9bc9f503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine</topic><topic>3-dimethyl-5</topic><topic>4-b]pyrazine</topic><topic>7-dithien-2-yl-thieno</topic><topic>9,9‐dioctylfluorene</topic><topic>9-dioctylfluorene</topic><topic>Applied sciences</topic><topic>conjugated polymers</topic><topic>Electronics</topic><topic>Exact sciences and technology</topic><topic>light-emitting diodes (LED)</topic><topic>Optoelectronic devices</topic><topic>Organic polymers</topic><topic>photovoltaic cells</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xia, Yangjun</creatorcontrib><creatorcontrib>Luo, Jie</creatorcontrib><creatorcontrib>Deng, Xianyu</creatorcontrib><creatorcontrib>Li, Xianzhen</creatorcontrib><creatorcontrib>Li, Dongyun</creatorcontrib><creatorcontrib>Zhu, Xuhui</creatorcontrib><creatorcontrib>Yang, Wei</creatorcontrib><creatorcontrib>Cao, Yong</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xia, Yangjun</au><au>Luo, Jie</au><au>Deng, Xianyu</au><au>Li, Xianzhen</au><au>Li, Dongyun</au><au>Zhu, Xuhui</au><au>Yang, Wei</au><au>Cao, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. Chem. Phys</addtitle><date>2006-03-03</date><risdate>2006</risdate><volume>207</volume><issue>5</issue><spage>511</spage><epage>520</epage><pages>511-520</pages><issn>1022-1352</issn><eissn>1521-3935</eissn><abstract>Novel readily soluble random low‐band‐gap conjugated copolymers (PFO–DTTP, Eg ≈ 1.77–2.00 eV) derived from 9,9‐dioctylfluorene (DOF) and 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine (DTTP) were prepared. The solutions and the solid thin films of the copolymers absorbed light from 300–690 nm. Prototype photovoltaic cells from solid state composite films with the copolymer PFO–DTTP30 and [6,6]‐phenyl C61 butyric acid methyl ester (PCBM) showed power conversion efficiencies up to 0.83% under an AM1.5 solar simulator (100 mW · cm−2). For electroluminescent devices, the emission peaks were around 734–780 nm. This indicates that the low band gap copolymers are promising materials for polymeric solar cells and deep red/near infrared light‐emitting diodes.
Synthesis of novel low‐band‐gap fluorene‐based copolymer.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/macp.200500517</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1352 |
| ispartof | Macromolecular chemistry and physics, 2006-03, Vol.207 (5), p.511-520 |
| issn | 1022-1352 1521-3935 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_macp_200500517 |
| source | Access via Wiley Online Library |
| subjects | 2,3‐dimethyl‐5,7‐dithien‐2‐yl‐thieno[3,4‐b]pyrazine 3-dimethyl-5 4-b]pyrazine 7-dithien-2-yl-thieno 9,9‐dioctylfluorene 9-dioctylfluorene Applied sciences conjugated polymers Electronics Exact sciences and technology light-emitting diodes (LED) Optoelectronic devices Organic polymers photovoltaic cells Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices |
| title | Novel Random Low-Band-Gap Fluorene-Based Copolymers for Deep Red/Near Infrared Light-Emitting Diodes and Bulk Heterojunction Photovoltaic Cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T16%3A09%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Novel%20Random%20Low-Band-Gap%20Fluorene-Based%20Copolymers%20for%20Deep%20Red/Near%20Infrared%20Light-Emitting%20Diodes%20and%20Bulk%20Heterojunction%20Photovoltaic%20Cells&rft.jtitle=Macromolecular%20chemistry%20and%20physics&rft.au=Xia,%20Yangjun&rft.date=2006-03-03&rft.volume=207&rft.issue=5&rft.spage=511&rft.epage=520&rft.pages=511-520&rft.issn=1022-1352&rft.eissn=1521-3935&rft_id=info:doi/10.1002/macp.200500517&rft_dat=%3Cwiley_cross%3EMACP200500517%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |