High-Temperature Propagation and Termination Kinetics of Styrene to High Conversion Investigated by Electron Paramagnetic Resonance Spectroscopy

The free radical bulk polymerization of styrene at 120 °C has been investigated over almost the entire conversion range using electron paramagnetic resonance spectroscopy, Fourier‐transform near‐infrared spectroscopy and gel permeation chromatography. The free radical concentration went through a sh...

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Veröffentlicht in:	Macromolecular chemistry and physics 2004-04, Vol.205 (6), p.778-785
Hauptverfasser:	Zetterlund, Per B., Yamauchi, Satoru, Yamada, Bunichiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences diffusion ESR/EPR Exact sciences and technology initiator efficiency Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts propagation termination
Online-Zugang:	Volltext
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