Anionic Polymerizations of 1-Adamantyl Methacrylate and 3-Methacryloyloxy-1,1′-biadamantane

Anionic polymerizations of 1‐adamantyl methacrylate (1) and 3‐methacryloyloxy‐1,1′‐biadamantane (2) were carried out in THF at −50 to −78 °C for 24 h. The initiator employed was either [1,1‐bis(4′‐trimethylsilylphenyl)‐3‐methylpentyl]lithium (3)/lithium chloride, or diphenylmethylpotassium. The poly...

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Veröffentlicht in:	Macromolecular chemistry and physics 2002-12, Vol.203 (16), p.2375-2384
Hauptverfasser:	Ishizone, Takashi, Tajima, Hiroyuki, Torimae, Hiroshi, Nakahama, Seiichi
Format:	Artikel
Sprache:	eng
Schlagworte:	1-adamantyl methacrylate 1′-biadamantane 3-methacryloyloxy-1 3‐methacryloyloxy‐1,1′‐biadamantane anionic polymerization Applied sciences block copolymers Exact sciences and technology glass transition Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts temperature
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