Synthesis and characterization of random and regular L-lysine-based polyamides
This paper deals with the synthesis of polyamides based on the natural diamine, L‐lysine, on the one hand, and diacids, adipic or glutaric, on the other hand. They were obtained by polycondensation of active diesters, pentachlorophenyl and pentafluorophenyl esters. L‐Lysine being non‐symmetrical, ar...
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| Veröffentlicht in: | Macromolecular chemistry and physics 1997-05, Vol.198 (5), p.1375-1389 |
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| container_title | Macromolecular chemistry and physics |
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| creator | Gachard, Isabelle Coutin, Bernard Sekiguchi, Hikaru |
| description | This paper deals with the synthesis of polyamides based on the natural diamine, L‐lysine, on the one hand, and diacids, adipic or glutaric, on the other hand. They were obtained by polycondensation of active diesters, pentachlorophenyl and pentafluorophenyl esters. L‐Lysine being non‐symmetrical, aregic (random) and syndioregic (“head‐to‐head, tail‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were obtained with molecular weights higher than 15000; isoregic (“head‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were prepared with lower molecular weights. |
| doi_str_mv | 10.1002/macp.1997.021980507 |
| format | Article |
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They were obtained by polycondensation of active diesters, pentachlorophenyl and pentafluorophenyl esters. L‐Lysine being non‐symmetrical, aregic (random) and syndioregic (“head‐to‐head, tail‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were obtained with molecular weights higher than 15000; isoregic (“head‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were prepared with lower molecular weights.</description><identifier>ISSN: 1022-1352</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.1997.021980507</identifier><language>eng</language><publisher>Zug: Hüthig & Wepf Verlag</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polycondensation ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Macromolecular chemistry and physics, 1997-05, Vol.198 (5), p.1375-1389</ispartof><rights>1997 Hüthig & Wepf Verlag, Zug</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3697-441cb8a87d072687f8f3e386384ed8a1a3d0a2de49814fce8ddc12606940af5a3</citedby><cites>FETCH-LOGICAL-c3697-441cb8a87d072687f8f3e386384ed8a1a3d0a2de49814fce8ddc12606940af5a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.1997.021980507$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.1997.021980507$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2642860$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Gachard, Isabelle</creatorcontrib><creatorcontrib>Coutin, Bernard</creatorcontrib><creatorcontrib>Sekiguchi, Hikaru</creatorcontrib><title>Synthesis and characterization of random and regular L-lysine-based polyamides</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>This paper deals with the synthesis of polyamides based on the natural diamine, L‐lysine, on the one hand, and diacids, adipic or glutaric, on the other hand. They were obtained by polycondensation of active diesters, pentachlorophenyl and pentafluorophenyl esters. L‐Lysine being non‐symmetrical, aregic (random) and syndioregic (“head‐to‐head, tail‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were obtained with molecular weights higher than 15000; isoregic (“head‐to‐tail”) poly(adipoyl‐L‐lysine)s and poly(glutaroyl‐L‐lysine)s were prepared with lower molecular weights.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqNkM9LwzAUx4soOKd_gZcevHa-JG2TXoQxdVPmFJzMW3hLUhdt15JUtP71dk6GR0_vwffH432C4JTAgADQ8xJVPSBZxgdASSYgAb4X9EhCScQylux3O1AaEZbQw-DI-1cAEJDxXjB7bNfNynjrQ1zrUK3QoWqMs1_Y2GodVnnoOqEqf2RnXt4LdOE0Klpv1yZaojc6rKuixdJq44-DgxwLb05-Zz94ur6ajybR9H58MxpOI8XSjEdxTNRSoOAaOE0Fz0XODBMpE7HRAgkyDUi1iTNB4lwZobUiNIU0iwHzBFk_YNte5Srvncll7WyJrpUE5AaJ3CCRGyRyh6RLnW1TNXqFRd59pqzfRWkaU5FCZ7vY2j5sYdr_NMu74ejh751oW2B9Yz53BejeZMoZT-RiNpa37DIeTRZz-cy-AdBphBc</recordid><startdate>199705</startdate><enddate>199705</enddate><creator>Gachard, Isabelle</creator><creator>Coutin, Bernard</creator><creator>Sekiguchi, Hikaru</creator><general>Hüthig & Wepf Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199705</creationdate><title>Synthesis and characterization of random and regular L-lysine-based polyamides</title><author>Gachard, Isabelle ; Coutin, Bernard ; Sekiguchi, Hikaru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3697-441cb8a87d072687f8f3e386384ed8a1a3d0a2de49814fce8ddc12606940af5a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polycondensation</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gachard, Isabelle</creatorcontrib><creatorcontrib>Coutin, Bernard</creatorcontrib><creatorcontrib>Sekiguchi, Hikaru</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gachard, Isabelle</au><au>Coutin, Bernard</au><au>Sekiguchi, Hikaru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of random and regular L-lysine-based polyamides</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. 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| ispartof | Macromolecular chemistry and physics, 1997-05, Vol.198 (5), p.1375-1389 |
| issn | 1022-1352 1521-3935 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_macp_1997_021980507 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polycondensation Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Synthesis and characterization of random and regular L-lysine-based polyamides |
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