γ-ray polymerization of a mesogenic methacrylate in the crystalline, liquid crystalline and liquid state: kinetics, molecular weight distribution and conversion-dependent phase behaviour

The γ‐ray polymerization of mesogenic 4‐methoxy‐4′‐(6‐methacryloyloxyhexyloxy)biphenyl (1) was investigated. 1 can be polymerized in the crystalline, in the liquid crystalline and in the molten state. The rate of polymerization increases from the crystalline to the melt phase. In order to reach 90%...

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Veröffentlicht in:	Macromolecular chemistry and physics 1996-09, Vol.197 (9), p.2753-2763
Hauptverfasser:	Hohn, Wilfried, Tieke, Bernd
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Physicochemistry of polymers Polymerization Polymers and radiations
Online-Zugang:	Volltext
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