Thermal degradation of polymers in the melt, 2. Kinetic approach to the formation of volatile oligomers by thermal degradation of polyisobutylene
The thermal degradation of polyisobutylene is characterized by kinetics consisting of four types of intramolecular hydrogen ion (back‐biting) of primary (p) and tertiary (t) terminal macroradicals (R p˙ and R t˙) and the successive β scission at the inner position of the main chain. This reaction af...
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| Veröffentlicht in: | Macromolecular chemistry and physics 1996-01, Vol.197 (1), p.215-222 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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