Functionalized initiators for group transfer and metal-free anionic polymerization for the synthesis of macromonomers: overview and new results

Vinylphenyloxy‐ and allyloxy‐substituted silyl ketene acetals are presented as new functionalized initiators for group transfer polymerization (GTP). All initiators initiated GTP of butyl acrylate in tetrahydrofuran with tetrabutylammonium cyanide as catalyst to yield butyl acrylate macromonomers wi...

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Veröffentlicht in:	Macromolecular chemistry and physics 1995-07, Vol.196 (7), p.2335-2347
Hauptverfasser:	Bandermann, Friedhelm, Beckelmann, Dirk, Broska, Dirk, Fieberg, Andreas, Roloff, Thorsten, Wolters, Dieter
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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