Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation
The synthesis and properties of segmented ABA triblock and (AB)n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved...
Gespeichert in:
| Veröffentlicht in: | Macromolecular chemistry and physics 1995-04, Vol.196 (4), p.1077-1091 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1091 |
|---|---|
| container_issue | 4 |
| container_start_page | 1077 |
| container_title | Macromolecular chemistry and physics |
| container_volume | 196 |
| creator | Eisenbach, Claus D. Göldel, Andreas Terskan-Reinold, Monika Schubert, Ulrich S. |
| description | The synthesis and properties of segmented ABA triblock and (AB)n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved by modification of conventional synthetic routes. In the presence of copper(I) ions these polymers formed mononuclear [Cu(I)(bpy)2] complexes in solution through self‐assembly. The complexed copolymers were microphase separated systems in bulk with nano to mesoscopic superstructures consisting of copper‐bpy complex aggregates in a polyether matrix. The thermal, mechanical and elastomer properties of the block copolymers varied with composition. |
| doi_str_mv | 10.1002/macp.1995.021960410 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_macp_1995_021960410</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_B2ZTP5CX_P</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3710-ee915914429f59e0e7960c0d3abaed300fda036fe53889aa397b935e1015604d3</originalsourceid><addsrcrecordid>eNqNUMFOwkAUbIwmIvoFXnrwoIfi2y5LWQ8m0iiSoJKI0XjZLO0rrLTbZrcG6te7iCEePb2XeTPzMuN5pwQ6BCC8LGRSdQjnrAMh4T3oEtjzWoSFJKCcsn23QxgGhLLw0Duy9gMA-sCjlrcc5GWy9JOyKvOmQGP9laoX_kxVjVGp0uhOupZKKz33Lc4L1LW98p8bXS_QKutLnTo8z4LSzKVWX7JWpfZnjR9_no8unLqoclz_oMfeQSZziye_s-293N1O4_tg_DQcxTfjIKERgQCRE8ZJtxvyjHEEjFyiBFIqZxJTCpClEmgvQ0b7fS4l5dHMhUQChLnoKW17dOubmNJag5mojCqkaQQBselLbPoSm77Eri-nOtuqKmkTmWdG6kTZnZR2exHhkaNdb2krlWPzH2fxcBNP_v4JtgbK1rjeGUizFL2IRky8Pg7FIHyfTlj8Jib0Gzm0jo4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation</title><source>Wiley Online Library</source><creator>Eisenbach, Claus D. ; Göldel, Andreas ; Terskan-Reinold, Monika ; Schubert, Ulrich S.</creator><creatorcontrib>Eisenbach, Claus D. ; Göldel, Andreas ; Terskan-Reinold, Monika ; Schubert, Ulrich S.</creatorcontrib><description>The synthesis and properties of segmented ABA triblock and (AB)n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved by modification of conventional synthetic routes. In the presence of copper(I) ions these polymers formed mononuclear [Cu(I)(bpy)2] complexes in solution through self‐assembly. The complexed copolymers were microphase separated systems in bulk with nano to mesoscopic superstructures consisting of copper‐bpy complex aggregates in a polyether matrix. The thermal, mechanical and elastomer properties of the block copolymers varied with composition.</description><identifier>ISSN: 1022-1352</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.1995.021960410</identifier><language>eng</language><publisher>Zug: Hüthig & Wepf Verlag</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Macromolecular chemistry and physics, 1995-04, Vol.196 (4), p.1077-1091</ispartof><rights>1995 Hüthig & Wepf Verlag, Zug</rights><rights>1995 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3710-ee915914429f59e0e7960c0d3abaed300fda036fe53889aa397b935e1015604d3</citedby><cites>FETCH-LOGICAL-c3710-ee915914429f59e0e7960c0d3abaed300fda036fe53889aa397b935e1015604d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.1995.021960410$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.1995.021960410$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3467197$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Eisenbach, Claus D.</creatorcontrib><creatorcontrib>Göldel, Andreas</creatorcontrib><creatorcontrib>Terskan-Reinold, Monika</creatorcontrib><creatorcontrib>Schubert, Ulrich S.</creatorcontrib><title>Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>The synthesis and properties of segmented ABA triblock and (AB)n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved by modification of conventional synthetic routes. In the presence of copper(I) ions these polymers formed mononuclear [Cu(I)(bpy)2] complexes in solution through self‐assembly. The complexed copolymers were microphase separated systems in bulk with nano to mesoscopic superstructures consisting of copper‐bpy complex aggregates in a polyether matrix. The thermal, mechanical and elastomer properties of the block copolymers varied with composition.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNqNUMFOwkAUbIwmIvoFXnrwoIfi2y5LWQ8m0iiSoJKI0XjZLO0rrLTbZrcG6te7iCEePb2XeTPzMuN5pwQ6BCC8LGRSdQjnrAMh4T3oEtjzWoSFJKCcsn23QxgGhLLw0Duy9gMA-sCjlrcc5GWy9JOyKvOmQGP9laoX_kxVjVGp0uhOupZKKz33Lc4L1LW98p8bXS_QKutLnTo8z4LSzKVWX7JWpfZnjR9_no8unLqoclz_oMfeQSZziye_s-293N1O4_tg_DQcxTfjIKERgQCRE8ZJtxvyjHEEjFyiBFIqZxJTCpClEmgvQ0b7fS4l5dHMhUQChLnoKW17dOubmNJag5mojCqkaQQBselLbPoSm77Eri-nOtuqKmkTmWdG6kTZnZR2exHhkaNdb2krlWPzH2fxcBNP_v4JtgbK1rjeGUizFL2IRky8Pg7FIHyfTlj8Jib0Gzm0jo4</recordid><startdate>199504</startdate><enddate>199504</enddate><creator>Eisenbach, Claus D.</creator><creator>Göldel, Andreas</creator><creator>Terskan-Reinold, Monika</creator><creator>Schubert, Ulrich S.</creator><general>Hüthig & Wepf Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199504</creationdate><title>Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation</title><author>Eisenbach, Claus D. ; Göldel, Andreas ; Terskan-Reinold, Monika ; Schubert, Ulrich S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3710-ee915914429f59e0e7960c0d3abaed300fda036fe53889aa397b935e1015604d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eisenbach, Claus D.</creatorcontrib><creatorcontrib>Göldel, Andreas</creatorcontrib><creatorcontrib>Terskan-Reinold, Monika</creatorcontrib><creatorcontrib>Schubert, Ulrich S.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eisenbach, Claus D.</au><au>Göldel, Andreas</au><au>Terskan-Reinold, Monika</au><au>Schubert, Ulrich S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. Chem. Phys</addtitle><date>1995-04</date><risdate>1995</risdate><volume>196</volume><issue>4</issue><spage>1077</spage><epage>1091</epage><pages>1077-1091</pages><issn>1022-1352</issn><eissn>1521-3935</eissn><abstract>The synthesis and properties of segmented ABA triblock and (AB)n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved by modification of conventional synthetic routes. In the presence of copper(I) ions these polymers formed mononuclear [Cu(I)(bpy)2] complexes in solution through self‐assembly. The complexed copolymers were microphase separated systems in bulk with nano to mesoscopic superstructures consisting of copper‐bpy complex aggregates in a polyether matrix. The thermal, mechanical and elastomer properties of the block copolymers varied with composition.</abstract><cop>Zug</cop><pub>Hüthig & Wepf Verlag</pub><doi>10.1002/macp.1995.021960410</doi><tpages>15</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1352 |
| ispartof | Macromolecular chemistry and physics, 1995-04, Vol.196 (4), p.1077-1091 |
| issn | 1022-1352 1521-3935 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_macp_1995_021960410 |
| source | Wiley Online Library |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T17%3A29%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Block%20copolymers%20with%20bipyridine%20containing%20segments:%20Synthesis%20and%20self-organization%20by%20Cu(I)%20complexation&rft.jtitle=Macromolecular%20chemistry%20and%20physics&rft.au=Eisenbach,%20Claus%20D.&rft.date=1995-04&rft.volume=196&rft.issue=4&rft.spage=1077&rft.epage=1091&rft.pages=1077-1091&rft.issn=1022-1352&rft.eissn=1521-3935&rft_id=info:doi/10.1002/macp.1995.021960410&rft_dat=%3Cistex_cross%3Eark_67375_WNG_B2ZTP5CX_P%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |