Synthesis and properties of liquid-crystalline AB-block copolymers poly[6-(4′-methoxy-4-biphenylyloxy)hexyl methacrylate]-block-polystyrene

Synthesis and properties of liquid-crystalline AB-block copolymers poly[6-(4′-methoxy-4-biphenylyloxy)hexyl methacrylate]-block-polystyrene

Liquid‐crystalline AB‐block copolymers poly[6‐(4′‐methoxy‐4‐biphenylyoxy)hexyl methacrylate]‐block‐polystyrene were synthesized by direct coupling of the homopolymers with functional end groups. Like the liquid‐crystalline homopolymer with mesogenic units in the side chain, all block copolymers show...

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Veröffentlicht in:Macromolecular chemistry and physics 1995-02, Vol.196 (2), p.679-690
Hauptverfasser: Van de Velde, Kathleen, Van Beylen, Marcel, Ottenburgs, Raoul, Samyn, Celest
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_issue 2
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container_title Macromolecular chemistry and physics
container_volume 196
creator Van de Velde, Kathleen
Van Beylen, Marcel
Ottenburgs, Raoul
Samyn, Celest
description Liquid‐crystalline AB‐block copolymers poly[6‐(4′‐methoxy‐4‐biphenylyoxy)hexyl methacrylate]‐block‐polystyrene were synthesized by direct coupling of the homopolymers with functional end groups. Like the liquid‐crystalline homopolymer with mesogenic units in the side chain, all block copolymers show a nematic mesophase. The transition temperatures are hardly affected by the composition and molecular weight of the block copolymers.
doi_str_mv 10.1002/macp.1995.021960223
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Synthesis and properties of liquid-crystalline AB-block copolymers poly[6-(4′-methoxy-4-biphenylyloxy)hexyl methacrylate]-block-polystyrene
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