Syntheses and ESR spectra of radicals produced in the thermal decomposition of tetraarylsuccinonitriles

Tetraarylsuccinonitriles 2a–e were synthesized via oxidative dimerization of diarylacetonitriles 1a–e in basic media. The thermal decomposition of 2 results in two identical cyanodiarylmethyl radicals 3. Both 1H and 13C NMR analyses of 1a–e and 2a–e and ESR spectra of 3a–e are presented and discusse...

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Veröffentlicht in:	Macromolecular chemistry and physics 1994-02, Vol.195 (2), p.463-473
Hauptverfasser:	Plaček, Jan, Szőcs, Ferenc, Braun, Dietrich, Skrzek, Thomas
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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