New side-group liquid-crystalline polymethacrylates

New side-group liquid-crystalline polymethacrylates

A new route of synthesis of liquid‐crystalline polymethacrylates was investigated. The synthetic route involved side‐group liquid‐crystalline polymethacrylates (LCPMA) with a turned ester group between the aromatic rings in the central unit of mesogens (2) as compared with the usual LCPMA (1). For a...

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Veröffentlicht in:Die Makromolekulare Chemie 1993-04, Vol.194 (4), p.1125-1135
Hauptverfasser: Rodekirch, Gerhard, Rübner, Joachim, Zschuppe, Veit, Wolff, Dietmar, Springer, Jürgen
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_end_page 1135
container_issue 4
container_start_page 1125
container_title Die Makromolekulare Chemie
container_volume 194
creator Rodekirch, Gerhard
Rübner, Joachim
Zschuppe, Veit
Wolff, Dietmar
Springer, Jürgen
description A new route of synthesis of liquid‐crystalline polymethacrylates was investigated. The synthetic route involved side‐group liquid‐crystalline polymethacrylates (LCPMA) with a turned ester group between the aromatic rings in the central unit of mesogens (2) as compared with the usual LCPMA (1). For a series of compounds of this type the liquid‐crystalline properties were investigated using differential scanning calorimetry, polarizing microscopy and X‐ray diffraction techniques. Generally stable smectic phases were found for these isomeric LCPMA. The described synthetic route opens possibilities to form new polymers from a wide field of educts.
doi_str_mv 10.1002/macp.1993.021940408
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
title New side-group liquid-crystalline polymethacrylates
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