Electroinitiated cationic polymerization by anodic dissolution
The polymerization of several monomers, such as styrene, α‐methylstyrene, lactones, isobutyl vinyl ether, and hexamethylcyclotrisiloxane, was carried out in H‐shaped cells equipped with sacrificial anodes. The solvents, dichloromethane or nitromethane, contained tetrabutylammonium perchlorate playin...
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| Veröffentlicht in: | Die Makromolekulare Chemie 1988-07, Vol.189 (7), p.1475-1484 |
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| container_issue | 7 |
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| container_title | Die Makromolekulare Chemie |
| container_volume | 189 |
| creator | Pierre, Gérard Limosin, Danièle Cheradame, Hervé |
| description | The polymerization of several monomers, such as styrene, α‐methylstyrene, lactones, isobutyl vinyl ether, and hexamethylcyclotrisiloxane, was carried out in H‐shaped cells equipped with sacrificial anodes. The solvents, dichloromethane or nitromethane, contained tetrabutylammonium perchlorate playing the role of supporting electrolyte. Among the different metals tested (Cu, Ag, Hg, Al, Pb, Sn), only mercury and aluminium anodes gave initiation. The conditions of the electrolysis, the nature of the monomers, and the results of special experiments carried out in the presence of a hindered pyridine demonstrate that the polymerization involves the electrophilic addition of the active species to the monomer followed by cationic chain growth. |
| doi_str_mv | 10.1002/macp.1988.021890701 |
| format | Article |
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The solvents, dichloromethane or nitromethane, contained tetrabutylammonium perchlorate playing the role of supporting electrolyte. Among the different metals tested (Cu, Ag, Hg, Al, Pb, Sn), only mercury and aluminium anodes gave initiation. The conditions of the electrolysis, the nature of the monomers, and the results of special experiments carried out in the presence of a hindered pyridine demonstrate that the polymerization involves the electrophilic addition of the active species to the monomer followed by cationic chain growth.</description><identifier>ISSN: 0025-116X</identifier><identifier>EISSN: 0025-116X</identifier><identifier>DOI: 10.1002/macp.1988.021890701</identifier><language>eng</language><publisher>Basel: Hüthig & Wepf Verlag</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Die Makromolekulare Chemie, 1988-07, Vol.189 (7), p.1475-1484</ispartof><rights>1988 Hüthig & Wepf Verlag, Basel</rights><rights>1988 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3011-3caf895edb59569e2e81f38078c8557c0a86101df6f895e1ec26852c9d28d06c3</citedby><cites>FETCH-LOGICAL-c3011-3caf895edb59569e2e81f38078c8557c0a86101df6f895e1ec26852c9d28d06c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.1988.021890701$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.1988.021890701$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7822030$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Pierre, Gérard</creatorcontrib><creatorcontrib>Limosin, Danièle</creatorcontrib><creatorcontrib>Cheradame, Hervé</creatorcontrib><title>Electroinitiated cationic polymerization by anodic dissolution</title><title>Die Makromolekulare Chemie</title><addtitle>Makromol. 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| identifier | ISSN: 0025-116X |
| ispartof | Die Makromolekulare Chemie, 1988-07, Vol.189 (7), p.1475-1484 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Electroinitiated cationic polymerization by anodic dissolution |
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