Metathesis degradation of partially cyclopropanated 1,4-polybutadiene: Consideration of side reactions in the calculation of block size distribution

(Z)‐1,4‐Polybutadiene was partially cyclopropanated with bis(iodomethyl)zinc and the polymer was degraded with (E)‐4‐octene in the presence of WCl6/(CH3)4Sn as catalyst. The products were identified by gas chromatography/mass spectrometry and determined by gas chromatography. The block size distribu...

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Veröffentlicht in:	Die Makromolekulare Chemie 1984-12, Vol.185 (12), p.2489-2496
Hauptverfasser:	Hummel, Klaus, Martl, Michael G., Chemelli, Ronald, Grießer, Herbert, Wukovnig, Siegfried, Zekoll, Haimo
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical reactions and properties Degradation Exact sciences and technology Organic polymers Physicochemistry of polymers
Online-Zugang:	Volltext
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