Segmented block copolymer models of uniform chain length and defined structure, 1. Synthesis and characterization
Segmented block copolymer models of defined structure with molecular weights up to ca. 4000 were synthesized by specific condensation of monofunctional derivatives of oligo condensation products of 4,4′‐isopropylidenediphenol (Bisphenol A) with terephthalic acid and oligomethylenes of uniform chain...
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| Veröffentlicht in: | Die Makromolekulare Chemie 1984-07, Vol.185 (7), p.1335-1360 |
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| container_issue | 7 |
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| container_title | Die Makromolekulare Chemie |
| container_volume | 185 |
| creator | Seliger, Hartmut Bitar, Mohammed Bassam Nguyen-Trong, Hao Marx, Alexander Roberts, Rolf Krüger, Jan-Kristian Unruh, Hans-Günther |
| description | Segmented block copolymer models of defined structure with molecular weights up to ca. 4000 were synthesized by specific condensation of monofunctional derivatives of oligo condensation products of 4,4′‐isopropylidenediphenol (Bisphenol A) with terephthalic acid and oligomethylenes of uniform chain length. The oligo(arylester) blocks were prepared by stepwise addition of oxyterephthaloyloxy‐1,4‐phenyleneisopropylidene‐1,4‐phenylene units using a suitable protection and activation scheme. Similarly, oligo(arylester)s containing isophthaloyl and phthaloyl units were obtained. Telechelic oligomethylene segments were prepared analogously by combining functional derivatives of decane. All compounds were characterized by chemical, spectroscopic, and chromatographic methods. |
| doi_str_mv | 10.1002/macp.1984.021850707 |
| format | Article |
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Similarly, oligo(arylester)s containing isophthaloyl and phthaloyl units were obtained. Telechelic oligomethylene segments were prepared analogously by combining functional derivatives of decane. 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Synthesis and characterization</atitle><jtitle>Die Makromolekulare Chemie</jtitle><addtitle>Makromol. Chem</addtitle><date>1984-07</date><risdate>1984</risdate><volume>185</volume><issue>7</issue><spage>1335</spage><epage>1360</epage><pages>1335-1360</pages><issn>0025-116X</issn><eissn>0025-116X</eissn><abstract>Segmented block copolymer models of defined structure with molecular weights up to ca. 4000 were synthesized by specific condensation of monofunctional derivatives of oligo condensation products of 4,4′‐isopropylidenediphenol (Bisphenol A) with terephthalic acid and oligomethylenes of uniform chain length. The oligo(arylester) blocks were prepared by stepwise addition of oxyterephthaloyloxy‐1,4‐phenyleneisopropylidene‐1,4‐phenylene units using a suitable protection and activation scheme. Similarly, oligo(arylester)s containing isophthaloyl and phthaloyl units were obtained. 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| identifier | ISSN: 0025-116X |
| ispartof | Die Makromolekulare Chemie, 1984-07, Vol.185 (7), p.1335-1360 |
| issn | 0025-116X 0025-116X |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_macp_1984_021850707 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Segmented block copolymer models of uniform chain length and defined structure, 1. Synthesis and characterization |
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