Stabilization of block copolymer micelles by UV and fast electron radiation

Stabilization of block copolymer micelles by UV and fast electron radiation

Micelles of a block copoymer poly(styrene/butadiene/styrene) with cores consisting of polybutadiene blocks were stabilized in dilute solutions by UV radiation in the presence of a photo‐initiator and also by fast electrons, and micelles of a block copolymer poly(styrene/ethene‐co‐1‐butene/styrene) w...

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Veröffentlicht in:Die Makromolekulare Chemie 1982-02, Vol.183 (2), p.399-408
Hauptverfasser: Tuzar, Zdeněk, Bednář, Bohumil, Koňák, Čestmír, Kubín, Miroslav, Svobodová, Štěpánka, Procházka, Karel
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container_end_page 408
container_issue 2
container_start_page 399
container_title Die Makromolekulare Chemie
container_volume 183
creator Tuzar, Zdeněk
Bednář, Bohumil
Koňák, Čestmír
Kubín, Miroslav
Svobodová, Štěpánka
Procházka, Karel
description Micelles of a block copoymer poly(styrene/butadiene/styrene) with cores consisting of polybutadiene blocks were stabilized in dilute solutions by UV radiation in the presence of a photo‐initiator and also by fast electrons, and micelles of a block copolymer poly(styrene/ethene‐co‐1‐butene/styrene) with cores formed by the aliphatic blocks were stabilized by fast electrons, in dilute solutions. Stabilization of micelles, i. e., crosslinking of the chains in micellar cores as well as the properties of stabilized micelles were studied by conventional light scattering, by light scattering photon correlation spectroscopy and by gel permeation chromatography.
doi_str_mv 10.1002/macp.1982.021830211
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title Stabilization of block copolymer micelles by UV and fast electron radiation
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