Vinyl polymerization. 238. Polymerization of acrylonitrile initiated by tetramethyl tetrazene and benzyl chloride
A study of the polymerization of acrylonitrile (AN) initiated by tetramethyl tetrazene (TMT) and benzyl chloride (BC) system was made. It was found that the polymerization proceeds through a radical mechanism. The initial rate of polymerization, Rp, followed the equation: \documentclass{article}\pag...
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| Veröffentlicht in: | Die Makromolekulare Chemie 1969-06, Vol.125 (1), p.161-169 |
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| container_title | Die Makromolekulare Chemie |
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| creator | Nakaya, Tadao Maki, Yoshikazu Imoto, Minoru |
| description | A study of the polymerization of acrylonitrile (AN) initiated by tetramethyl tetrazene (TMT) and benzyl chloride (BC) system was made. It was found that the polymerization proceeds through a radical mechanism. The initial rate of polymerization, Rp, followed the equation:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
From the results the initiation mechanism was discussed.
Eine Untersuchung über die durch das System Tetramethyltetrazen (TMT) und Benzylchlorid initiierte Polymerisation von Acrylnitril (AN) wurde durchgeführt. Es ergab sich, daß die Polymerisation nach einem radikalischen Mechanismus verläuft. Die Anfangspolymerisationsgeschwindigkeit, Rp, folgt der Gleichung:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
Auf Grund dieser Ergebnisse wurde der Startmechanismus diskutiert. |
| doi_str_mv | 10.1002/macp.1969.021250115 |
| format | Article |
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\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
From the results the initiation mechanism was discussed.
Eine Untersuchung über die durch das System Tetramethyltetrazen (TMT) und Benzylchlorid initiierte Polymerisation von Acrylnitril (AN) wurde durchgeführt. Es ergab sich, daß die Polymerisation nach einem radikalischen Mechanismus verläuft. Die Anfangspolymerisationsgeschwindigkeit, Rp, folgt der Gleichung:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
Auf Grund dieser Ergebnisse wurde der Startmechanismus diskutiert.</description><identifier>ISSN: 0025-116X</identifier><identifier>EISSN: 0025-116X</identifier><identifier>DOI: 10.1002/macp.1969.021250115</identifier><language>eng</language><publisher>Basel: Hüthig & Wepf Verlag</publisher><ispartof>Die Makromolekulare Chemie, 1969-06, Vol.125 (1), p.161-169</ispartof><rights>1969 Hüthig & Wepf Verlag, Basel</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2535-40ff75e3f842abcdece490e341622b365b7e3a4777a0f97b079f01a5b03a6cf23</citedby><cites>FETCH-LOGICAL-c2535-40ff75e3f842abcdece490e341622b365b7e3a4777a0f97b079f01a5b03a6cf23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.1969.021250115$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.1969.021250115$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids></links><search><creatorcontrib>Nakaya, Tadao</creatorcontrib><creatorcontrib>Maki, Yoshikazu</creatorcontrib><creatorcontrib>Imoto, Minoru</creatorcontrib><title>Vinyl polymerization. 238. Polymerization of acrylonitrile initiated by tetramethyl tetrazene and benzyl chloride</title><title>Die Makromolekulare Chemie</title><addtitle>Makromol. Chem</addtitle><description>A study of the polymerization of acrylonitrile (AN) initiated by tetramethyl tetrazene (TMT) and benzyl chloride (BC) system was made. It was found that the polymerization proceeds through a radical mechanism. The initial rate of polymerization, Rp, followed the equation:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
From the results the initiation mechanism was discussed.
Eine Untersuchung über die durch das System Tetramethyltetrazen (TMT) und Benzylchlorid initiierte Polymerisation von Acrylnitril (AN) wurde durchgeführt. Es ergab sich, daß die Polymerisation nach einem radikalischen Mechanismus verläuft. Die Anfangspolymerisationsgeschwindigkeit, Rp, folgt der Gleichung:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
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\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
From the results the initiation mechanism was discussed.
Eine Untersuchung über die durch das System Tetramethyltetrazen (TMT) und Benzylchlorid initiierte Polymerisation von Acrylnitril (AN) wurde durchgeführt. Es ergab sich, daß die Polymerisation nach einem radikalischen Mechanismus verläuft. Die Anfangspolymerisationsgeschwindigkeit, Rp, folgt der Gleichung:
\documentclass{article}\pagestyle{empty}\begin{document}$$R_p = k\left[ {TMT} \right]^{0.59} \left[ {BC} \right]^{0.5} \left[ {AN} \right]^{1.30} $$\end{document}
Auf Grund dieser Ergebnisse wurde der Startmechanismus diskutiert.</abstract><cop>Basel</cop><pub>Hüthig & Wepf Verlag</pub><doi>10.1002/macp.1969.021250115</doi><tpages>9</tpages></addata></record> |
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| ispartof | Die Makromolekulare Chemie, 1969-06, Vol.125 (1), p.161-169 |
| issn | 0025-116X 0025-116X |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_macp_1969_021250115 |
| source | Wiley Online Library All Journals |
| title | Vinyl polymerization. 238. Polymerization of acrylonitrile initiated by tetramethyl tetrazene and benzyl chloride |
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