A case of nitridation, carburization and oxidation on a stainless steel
A case of corrosion was studied on stainless steel tubes, exposed to a nitriding, carburizing and oxidizing environment (mainly NH3 and CO2) at 390–450°C. Due to the high nitriding potential prior formation of internally nitrided layers occurs, at higher temperatures (> about 425°C) under precipi...
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Veröffentlicht in: | Materials and corrosion 2005-06, Vol.56 (6), p.384-388 |
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description | A case of corrosion was studied on stainless steel tubes, exposed to a nitriding, carburizing and oxidizing environment (mainly NH3 and CO2) at 390–450°C. Due to the high nitriding potential prior formation of internally nitrided layers occurs, at higher temperatures (> about 425°C) under precipitation of CrN in the layer and at lower temperatures under formation of the γN‐phase, i.e. austenite with high N‐content and expanded lattice. The latter process causes more severe corrosion, due to the high expansion, the stresses in the nitrided layers lead to bursting and repeated spalling of the scales. Carburization and oxidation are less important. The carburization is slower than nitridation, Fe3C formation is observed and carbon deposition. Also the oxidation by CO2 is slow and converts the nitrides and carbides formed before, to unprotective oxide flakes. |
doi_str_mv | 10.1002/maco.200403849 |
format | Article |
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J.</creator><creatorcontrib>Grabke, H. J.</creatorcontrib><description>A case of corrosion was studied on stainless steel tubes, exposed to a nitriding, carburizing and oxidizing environment (mainly NH3 and CO2) at 390–450°C. Due to the high nitriding potential prior formation of internally nitrided layers occurs, at higher temperatures (> about 425°C) under precipitation of CrN in the layer and at lower temperatures under formation of the γN‐phase, i.e. austenite with high N‐content and expanded lattice. The latter process causes more severe corrosion, due to the high expansion, the stresses in the nitrided layers lead to bursting and repeated spalling of the scales. Carburization and oxidation are less important. The carburization is slower than nitridation, Fe3C formation is observed and carbon deposition. Also the oxidation by CO2 is slow and converts the nitrides and carbides formed before, to unprotective oxide flakes.</description><identifier>ISSN: 0947-5117</identifier><identifier>EISSN: 1521-4176</identifier><identifier>DOI: 10.1002/maco.200403849</identifier><identifier>CODEN: MTCREQ</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; carburization ; Corrosion ; Corrosion environments ; Corrosion mechanisms ; Exact sciences and technology ; Heat treatment ; Metals. Metallurgy ; nitridation ; nitrided layer ; oxidation ; Production techniques ; spalling ; stainless steel ; Thermochemical treatment and diffusion treatment</subject><ispartof>Materials and corrosion, 2005-06, Vol.56 (6), p.384-388</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4239-e2d6aafbe3cc3a1814a1f4fa84cf2bf07fe68b3178a7c0963f5a06de0dcb56673</citedby><cites>FETCH-LOGICAL-c4239-e2d6aafbe3cc3a1814a1f4fa84cf2bf07fe68b3178a7c0963f5a06de0dcb56673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmaco.200403849$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16865136$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Grabke, H. J.</creatorcontrib><title>A case of nitridation, carburization and oxidation on a stainless steel</title><title>Materials and corrosion</title><addtitle>Materials and Corrosion</addtitle><description>A case of corrosion was studied on stainless steel tubes, exposed to a nitriding, carburizing and oxidizing environment (mainly NH3 and CO2) at 390–450°C. Due to the high nitriding potential prior formation of internally nitrided layers occurs, at higher temperatures (> about 425°C) under precipitation of CrN in the layer and at lower temperatures under formation of the γN‐phase, i.e. austenite with high N‐content and expanded lattice. The latter process causes more severe corrosion, due to the high expansion, the stresses in the nitrided layers lead to bursting and repeated spalling of the scales. Carburization and oxidation are less important. The carburization is slower than nitridation, Fe3C formation is observed and carbon deposition. Also the oxidation by CO2 is slow and converts the nitrides and carbides formed before, to unprotective oxide flakes.</description><subject>Applied sciences</subject><subject>carburization</subject><subject>Corrosion</subject><subject>Corrosion environments</subject><subject>Corrosion mechanisms</subject><subject>Exact sciences and technology</subject><subject>Heat treatment</subject><subject>Metals. Metallurgy</subject><subject>nitridation</subject><subject>nitrided layer</subject><subject>oxidation</subject><subject>Production techniques</subject><subject>spalling</subject><subject>stainless steel</subject><subject>Thermochemical treatment and diffusion treatment</subject><issn>0947-5117</issn><issn>1521-4176</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkD1PwzAQhi0EEqWwMmdhI8UXO3YyVgUCUqFSBXS0Lo4tGdKksoto-fWkBBU2pvt83ju9hJwDHQGlydUSdTtKKOWUZTw_IANIE4g5SHFIBjTnMk4B5DE5CeGVUoCc8QEpxpHGYKLWRo1be1fh2rXNZdf05bt3n99lhE0VtZufYbRrRGGNrqlNCF1mTH1KjizWwZz9xCF5vr15mtzF01lxPxlPY80TlscmqQSiLQ3TmiFkwBEst5hxbZPSUmmNyEoGMkOpaS6YTZGKytBKl6kQkg3JqNfVvg3BG6tW3i3RbxVQtbNB7WxQexs64KIHVhg01tZjo134pUQmUmCi28v7vQ9Xm-0_quphPJn9vRH3rOu82OxZ9G-qe1mmavFYKPlSFMl8MVfX7Aufk36s</recordid><startdate>200506</startdate><enddate>200506</enddate><creator>Grabke, H. J.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200506</creationdate><title>A case of nitridation, carburization and oxidation on a stainless steel</title><author>Grabke, H. J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4239-e2d6aafbe3cc3a1814a1f4fa84cf2bf07fe68b3178a7c0963f5a06de0dcb56673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>carburization</topic><topic>Corrosion</topic><topic>Corrosion environments</topic><topic>Corrosion mechanisms</topic><topic>Exact sciences and technology</topic><topic>Heat treatment</topic><topic>Metals. Metallurgy</topic><topic>nitridation</topic><topic>nitrided layer</topic><topic>oxidation</topic><topic>Production techniques</topic><topic>spalling</topic><topic>stainless steel</topic><topic>Thermochemical treatment and diffusion treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grabke, H. J.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Materials and corrosion</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grabke, H. J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A case of nitridation, carburization and oxidation on a stainless steel</atitle><jtitle>Materials and corrosion</jtitle><addtitle>Materials and Corrosion</addtitle><date>2005-06</date><risdate>2005</risdate><volume>56</volume><issue>6</issue><spage>384</spage><epage>388</epage><pages>384-388</pages><issn>0947-5117</issn><eissn>1521-4176</eissn><coden>MTCREQ</coden><abstract>A case of corrosion was studied on stainless steel tubes, exposed to a nitriding, carburizing and oxidizing environment (mainly NH3 and CO2) at 390–450°C. Due to the high nitriding potential prior formation of internally nitrided layers occurs, at higher temperatures (> about 425°C) under precipitation of CrN in the layer and at lower temperatures under formation of the γN‐phase, i.e. austenite with high N‐content and expanded lattice. The latter process causes more severe corrosion, due to the high expansion, the stresses in the nitrided layers lead to bursting and repeated spalling of the scales. Carburization and oxidation are less important. The carburization is slower than nitridation, Fe3C formation is observed and carbon deposition. Also the oxidation by CO2 is slow and converts the nitrides and carbides formed before, to unprotective oxide flakes.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/maco.200403849</doi><tpages>5</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Applied sciences carburization Corrosion Corrosion environments Corrosion mechanisms Exact sciences and technology Heat treatment Metals. Metallurgy nitridation nitrided layer oxidation Production techniques spalling stainless steel Thermochemical treatment and diffusion treatment |
title | A case of nitridation, carburization and oxidation on a stainless steel |
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